Ruthenium(III) Chloride Catalyzed Acylation of Alcohols, Phenols, and Thiols in Room Temperature Ionic Liquids

Ruthenium(III) chloride-catalyzed acylation of a variety of alcohols, phenols, and thiols was achieved in high yields under mild conditions (room temperature) in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF(6)]). The ionic liquid and ruthenium catalyst can be recycled...

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Detalles Bibliográficos
Autores principales: Xi, Zhiwen, Hao, Wenyan, Wang, Pingping, Cai, Mingzhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6255024/
https://www.ncbi.nlm.nih.gov/pubmed/19783941
http://dx.doi.org/10.3390/molecules14093528
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author Xi, Zhiwen
Hao, Wenyan
Wang, Pingping
Cai, Mingzhong
author_facet Xi, Zhiwen
Hao, Wenyan
Wang, Pingping
Cai, Mingzhong
author_sort Xi, Zhiwen
collection PubMed
description Ruthenium(III) chloride-catalyzed acylation of a variety of alcohols, phenols, and thiols was achieved in high yields under mild conditions (room temperature) in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF(6)]). The ionic liquid and ruthenium catalyst can be recycled at least 10 times. Our system not only solves the basic problem of ruthenium catalyst reuse, but also avoids the use of volatile acetonitrile as solvent.
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spelling pubmed-62550242018-11-30 Ruthenium(III) Chloride Catalyzed Acylation of Alcohols, Phenols, and Thiols in Room Temperature Ionic Liquids Xi, Zhiwen Hao, Wenyan Wang, Pingping Cai, Mingzhong Molecules Article Ruthenium(III) chloride-catalyzed acylation of a variety of alcohols, phenols, and thiols was achieved in high yields under mild conditions (room temperature) in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF(6)]). The ionic liquid and ruthenium catalyst can be recycled at least 10 times. Our system not only solves the basic problem of ruthenium catalyst reuse, but also avoids the use of volatile acetonitrile as solvent. Molecular Diversity Preservation International 2009-09-10 /pmc/articles/PMC6255024/ /pubmed/19783941 http://dx.doi.org/10.3390/molecules14093528 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Xi, Zhiwen
Hao, Wenyan
Wang, Pingping
Cai, Mingzhong
Ruthenium(III) Chloride Catalyzed Acylation of Alcohols, Phenols, and Thiols in Room Temperature Ionic Liquids
title Ruthenium(III) Chloride Catalyzed Acylation of Alcohols, Phenols, and Thiols in Room Temperature Ionic Liquids
title_full Ruthenium(III) Chloride Catalyzed Acylation of Alcohols, Phenols, and Thiols in Room Temperature Ionic Liquids
title_fullStr Ruthenium(III) Chloride Catalyzed Acylation of Alcohols, Phenols, and Thiols in Room Temperature Ionic Liquids
title_full_unstemmed Ruthenium(III) Chloride Catalyzed Acylation of Alcohols, Phenols, and Thiols in Room Temperature Ionic Liquids
title_short Ruthenium(III) Chloride Catalyzed Acylation of Alcohols, Phenols, and Thiols in Room Temperature Ionic Liquids
title_sort ruthenium(iii) chloride catalyzed acylation of alcohols, phenols, and thiols in room temperature ionic liquids
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6255024/
https://www.ncbi.nlm.nih.gov/pubmed/19783941
http://dx.doi.org/10.3390/molecules14093528
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AT haowenyan rutheniumiiichloridecatalyzedacylationofalcoholsphenolsandthiolsinroomtemperatureionicliquids
AT wangpingping rutheniumiiichloridecatalyzedacylationofalcoholsphenolsandthiolsinroomtemperatureionicliquids
AT caimingzhong rutheniumiiichloridecatalyzedacylationofalcoholsphenolsandthiolsinroomtemperatureionicliquids

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