The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines

N-Aryl-S,S-dimethylsulfimides 3 (Ar = 4-NO(2)C(6)H(4)), 4 (Ar = Ph) and 5 (Ar = 4-Tol) react with Appel salt 1 to give the corresponding N-aryl-(4-chloro-5H-1,2,3-dithiazolylidene)benzenamines 8 (Ar = 4-NO2C6H4), 9 (Ar = Ph) and 10 (Ar = 4-Tol) in 84, 94 and 87% yields, respectively. The reaction pr...

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Detalles Bibliográficos
Autores principales: Kalogirou, Andreas S., Koutentis, Panayiotis A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6255028/
https://www.ncbi.nlm.nih.gov/pubmed/19633609
http://dx.doi.org/10.3390/molecules14072356
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author Kalogirou, Andreas S.
Koutentis, Panayiotis A.
author_facet Kalogirou, Andreas S.
Koutentis, Panayiotis A.
author_sort Kalogirou, Andreas S.
collection PubMed
description N-Aryl-S,S-dimethylsulfimides 3 (Ar = 4-NO(2)C(6)H(4)), 4 (Ar = Ph) and 5 (Ar = 4-Tol) react with Appel salt 1 to give the corresponding N-aryl-(4-chloro-5H-1,2,3-dithiazolylidene)benzenamines 8 (Ar = 4-NO2C6H4), 9 (Ar = Ph) and 10 (Ar = 4-Tol) in 84, 94 and 87% yields, respectively. The reaction proceeds in the absence of base and a proposed reaction mechanism is given.
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spelling pubmed-62550282018-11-30 The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines Kalogirou, Andreas S. Koutentis, Panayiotis A. Molecules Article N-Aryl-S,S-dimethylsulfimides 3 (Ar = 4-NO(2)C(6)H(4)), 4 (Ar = Ph) and 5 (Ar = 4-Tol) react with Appel salt 1 to give the corresponding N-aryl-(4-chloro-5H-1,2,3-dithiazolylidene)benzenamines 8 (Ar = 4-NO2C6H4), 9 (Ar = Ph) and 10 (Ar = 4-Tol) in 84, 94 and 87% yields, respectively. The reaction proceeds in the absence of base and a proposed reaction mechanism is given. Molecular Diversity Preservation International 2009-07-02 /pmc/articles/PMC6255028/ /pubmed/19633609 http://dx.doi.org/10.3390/molecules14072356 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Kalogirou, Andreas S.
Koutentis, Panayiotis A.
The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines
title The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines
title_full The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines
title_fullStr The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines
title_full_unstemmed The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines
title_short The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines
title_sort reaction of 4,5-dichloro-1,2,3-dithiazolium chloride with sulfimides: a new synthesis of n-aryl-1,2,3-dithiazolimines
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6255028/
https://www.ncbi.nlm.nih.gov/pubmed/19633609
http://dx.doi.org/10.3390/molecules14072356
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