Catalytic Epoxidation of a Technical Mixture of Methyl Oleate and Methyl Linoleate in Ionic Liquids Using MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) as Catalyst and NaHCO(3) as co-Catalyst

The oxo-diperoxo molybdenum(VI) complex MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) was prepared and characterized by elemental analysis, IR and UV-Vis spectra. The ionic liquids (ILs) [bmim][BF(4)], [hydemim][BF(4)], and [bmim][PF(6)] were characterized by (1)H-NMR and UV-Vis spectra. The epoxidation of...

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Autores principales: Cai, Shuang-Fei, Wang, Li-Sheng, Fan, Chuan-Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6255259/
https://www.ncbi.nlm.nih.gov/pubmed/19701136
http://dx.doi.org/10.3390/molecules14082935
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author Cai, Shuang-Fei
Wang, Li-Sheng
Fan, Chuan-Lei
author_facet Cai, Shuang-Fei
Wang, Li-Sheng
Fan, Chuan-Lei
author_sort Cai, Shuang-Fei
collection PubMed
description The oxo-diperoxo molybdenum(VI) complex MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) was prepared and characterized by elemental analysis, IR and UV-Vis spectra. The ionic liquids (ILs) [bmim][BF(4)], [hydemim][BF(4)], and [bmim][PF(6)] were characterized by (1)H-NMR and UV-Vis spectra. The epoxidation of a technical mixture of methyl oleate and methyl linoleate with H(2)O(2), in [bmim][BF(4)], [hydemim][BF(4)] and [bmim][PF(6)], catalyzed by MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) and with NaHCO(3) as co-catalyst has been studied for the first time. It was found that high conversions of methyl oleate and methyl linoleate to their respective oxidation products, as well as the total selectivity of their oxidation products to oxirane in [hydemim][BF(4)] were obtained. Also, the IL phases containing the Mo(VI) catalyst can be readily recycled by washing with diethyl ether and drying, and the Mo(VI) catalyst can be reused at least five times.
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spelling pubmed-62552592018-11-30 Catalytic Epoxidation of a Technical Mixture of Methyl Oleate and Methyl Linoleate in Ionic Liquids Using MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) as Catalyst and NaHCO(3) as co-Catalyst Cai, Shuang-Fei Wang, Li-Sheng Fan, Chuan-Lei Molecules Article The oxo-diperoxo molybdenum(VI) complex MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) was prepared and characterized by elemental analysis, IR and UV-Vis spectra. The ionic liquids (ILs) [bmim][BF(4)], [hydemim][BF(4)], and [bmim][PF(6)] were characterized by (1)H-NMR and UV-Vis spectra. The epoxidation of a technical mixture of methyl oleate and methyl linoleate with H(2)O(2), in [bmim][BF(4)], [hydemim][BF(4)] and [bmim][PF(6)], catalyzed by MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) and with NaHCO(3) as co-catalyst has been studied for the first time. It was found that high conversions of methyl oleate and methyl linoleate to their respective oxidation products, as well as the total selectivity of their oxidation products to oxirane in [hydemim][BF(4)] were obtained. Also, the IL phases containing the Mo(VI) catalyst can be readily recycled by washing with diethyl ether and drying, and the Mo(VI) catalyst can be reused at least five times. Molecular Diversity Preservation International 2009-08-10 /pmc/articles/PMC6255259/ /pubmed/19701136 http://dx.doi.org/10.3390/molecules14082935 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Cai, Shuang-Fei
Wang, Li-Sheng
Fan, Chuan-Lei
Catalytic Epoxidation of a Technical Mixture of Methyl Oleate and Methyl Linoleate in Ionic Liquids Using MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) as Catalyst and NaHCO(3) as co-Catalyst
title Catalytic Epoxidation of a Technical Mixture of Methyl Oleate and Methyl Linoleate in Ionic Liquids Using MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) as Catalyst and NaHCO(3) as co-Catalyst
title_full Catalytic Epoxidation of a Technical Mixture of Methyl Oleate and Methyl Linoleate in Ionic Liquids Using MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) as Catalyst and NaHCO(3) as co-Catalyst
title_fullStr Catalytic Epoxidation of a Technical Mixture of Methyl Oleate and Methyl Linoleate in Ionic Liquids Using MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) as Catalyst and NaHCO(3) as co-Catalyst
title_full_unstemmed Catalytic Epoxidation of a Technical Mixture of Methyl Oleate and Methyl Linoleate in Ionic Liquids Using MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) as Catalyst and NaHCO(3) as co-Catalyst
title_short Catalytic Epoxidation of a Technical Mixture of Methyl Oleate and Methyl Linoleate in Ionic Liquids Using MoO(O(2))(2)·2QOH (QOH = 8-quinilinol) as Catalyst and NaHCO(3) as co-Catalyst
title_sort catalytic epoxidation of a technical mixture of methyl oleate and methyl linoleate in ionic liquids using moo(o(2))(2)·2qoh (qoh = 8-quinilinol) as catalyst and nahco(3) as co-catalyst
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6255259/
https://www.ncbi.nlm.nih.gov/pubmed/19701136
http://dx.doi.org/10.3390/molecules14082935
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