Cargando…
Al(OCArF3)(3) – a thermally stable Lewis superacid
The adduct free Lewis superacid Al(OCArF3)(3) was obtained by the reaction of ArF3COH with AlEt(3) and fully characterized (Ar(F) = C(6)F(5)). It comprises a high thermal stability up to 180 °C and a distinct reactivity towards Lewis bases, as exemplified by the isolation of the neutral adducts Al(O...
Autores principales: | Kögel, Julius F., Timoshkin, Alexey Y., Schröder, Artem, Lork, Enno, Beckmann, Jens |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6256356/ https://www.ncbi.nlm.nih.gov/pubmed/30568768 http://dx.doi.org/10.1039/c8sc02981d |
Ejemplares similares
-
Lewis Superacidic Tellurenyl Cation‐Induced Electrophilic Activation of an Inert Carborane
por: Hejda, Martin, et al.
Publicado: (2021) -
Isolable Silicon‐Based Polycations with Lewis Superacidity
por: Hermannsdorfer, André, et al.
Publicado: (2020) -
A free boratriptycene-type Lewis superacid
por: Henkelmann, Marcel, et al.
Publicado: (2021) -
Insights on the Lewis Superacid Al(OTeF(5))(3): Solvent Adducts, Characterization and Properties
por: Hoffmann, Kurt F., et al.
Publicado: (2022) -
Transient Phosphenium and Arsenium Ions versus Stable Stibenium and Bismuthenium Ions
por: Olaru, Marian, et al.
Publicado: (2019)