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Synthesis of the first Zn(6)-hexagon sandwich-tungstoantimonate via rearrangement of a non-lacunary Krebs-type polyoxotungstate

A novel synthetic pathway to obtain the first Zn(6) hexagon tungstoantimonate [(Zn(H(2)O))(6)(B-α-SbW(9)O(33))(2)](6–) ([Zn(6)-α-SbW(9)] (1)) via rearrangement of a non-lacunary Krebs-POM precursor (C(12)N(4)H(11))(4)K(4)[(Mn(H(2)O)(3))(2)((Mn(0.5)W(0.5))O(2))(2)(B-β-SbW(9)O(33))(2)] ([Mn-β-SbW(9)])...

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Detalles Bibliográficos
Autores principales:	Tanuhadi, Elias, Roller, Alexander, Giester, Gerald, Kampatsikas, Ioannis, Rompel, Annette
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6256361/ https://www.ncbi.nlm.nih.gov/pubmed/30334554 http://dx.doi.org/10.1039/c8dt02787k

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