Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH(2)OH·HCl and TiO(2)

Aromatic aldehydes bearing electron-donating groups are easily converted into their respective nitriles using NH(2)OH·HCl and TiO(2) under microwave irradiation, while those bearing an electron-withdrawing group give the corresponding oximes.

Detalles Bibliográficos
Autores principales: Hoelz, Lucas Villas-Boas, Gonçalves, Biank Tomaz, Barros, José Celestino, da Silva, Joaquim Fernando Mendes
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257113/
https://www.ncbi.nlm.nih.gov/pubmed/20110874
http://dx.doi.org/10.3390/molecules15010094
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author Hoelz, Lucas Villas-Boas
Gonçalves, Biank Tomaz
Barros, José Celestino
da Silva, Joaquim Fernando Mendes
author_facet Hoelz, Lucas Villas-Boas
Gonçalves, Biank Tomaz
Barros, José Celestino
da Silva, Joaquim Fernando Mendes
author_sort Hoelz, Lucas Villas-Boas
collection PubMed
description Aromatic aldehydes bearing electron-donating groups are easily converted into their respective nitriles using NH(2)OH·HCl and TiO(2) under microwave irradiation, while those bearing an electron-withdrawing group give the corresponding oximes.
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spelling pubmed-62571132018-12-03 Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH(2)OH·HCl and TiO(2) Hoelz, Lucas Villas-Boas Gonçalves, Biank Tomaz Barros, José Celestino da Silva, Joaquim Fernando Mendes Molecules Communication Aromatic aldehydes bearing electron-donating groups are easily converted into their respective nitriles using NH(2)OH·HCl and TiO(2) under microwave irradiation, while those bearing an electron-withdrawing group give the corresponding oximes. Molecular Diversity Preservation International 2009-12-29 /pmc/articles/PMC6257113/ /pubmed/20110874 http://dx.doi.org/10.3390/molecules15010094 Text en © 2010 by the authors; http://creativecommons.org/licenses/by/3.0/ licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Communication
Hoelz, Lucas Villas-Boas
Gonçalves, Biank Tomaz
Barros, José Celestino
da Silva, Joaquim Fernando Mendes
Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH(2)OH·HCl and TiO(2)
title Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH(2)OH·HCl and TiO(2)
title_full Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH(2)OH·HCl and TiO(2)
title_fullStr Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH(2)OH·HCl and TiO(2)
title_full_unstemmed Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH(2)OH·HCl and TiO(2)
title_short Solvent Free, Microwave Assisted Conversion of Aldehydes into Nitriles and Oximes in the Presence of NH(2)OH·HCl and TiO(2)
title_sort solvent free, microwave assisted conversion of aldehydes into nitriles and oximes in the presence of nh(2)oh·hcl and tio(2)
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257113/
https://www.ncbi.nlm.nih.gov/pubmed/20110874
http://dx.doi.org/10.3390/molecules15010094
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