Synthesis and Structure of D(3h)-Symmetric Triptycene Trimaleimide

A new D(3h) symmetric triptycene derivative has been synthesized with the aim of obtaining molecules that are able to assemble into porous structures, and can be used in the development of new ligands. The synthesis involves a Diels-Alder reaction as the key step, followed by an oxidation and the fo...

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Detalles Bibliográficos
Autores principales: Zonta, Cristiano, De Lucchi, Ottorino, Linden, Anthony, Lutz, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257117/
https://www.ncbi.nlm.nih.gov/pubmed/20110885
http://dx.doi.org/10.3390/molecules15010226
Descripción
Sumario:A new D(3h) symmetric triptycene derivative has been synthesized with the aim of obtaining molecules that are able to assemble into porous structures, and can be used in the development of new ligands. The synthesis involves a Diels-Alder reaction as the key step, followed by an oxidation and the formation of a maleimide ring. Triptycene trimaleimide furnished single crystals which have been analyzed by means of X-ray diffraction.

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