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Ultrasonic Method for the Preparation of Organic Porphyrin Nanoparticles †

We report the synthesis and optical properties of organic porphyrin nanoparticles with narrow size distribution and good dispersibility. Nanoparticles were produced by a combination of precipitation and sonication, termed the “ultrasonic method”. The resulting [tetrakis(para-chlorophenyl)porphyrin]T...

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Detalles Bibliográficos
Autores principales: Kashani-Motlagh, Mohamad Mehdi, Rahimi, Rahmatollah, Kachousangi, Marziye Javaheri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257125/
https://www.ncbi.nlm.nih.gov/pubmed/20110879
http://dx.doi.org/10.3390/molecules15010280
Descripción
Sumario:We report the synthesis and optical properties of organic porphyrin nanoparticles with narrow size distribution and good dispersibility. Nanoparticles were produced by a combination of precipitation and sonication, termed the “ultrasonic method”. The resulting [tetrakis(para-chlorophenyl)porphyrin]TClPP nanoparticles were stable in solution without precipitation for at least 30 days. No self aggregation of the constituent porphyrin chromophores was observed. The TClPP nanoparticles exhibited interesting optical properties, particulalrly a large bathochromic shift in the absorption spectra.