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Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins

The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)(2)/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins...

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Detalles Bibliográficos
Autores principales: Obora, Yasushi, Ishii, Yasutaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257262/
https://www.ncbi.nlm.nih.gov/pubmed/20335996
http://dx.doi.org/10.3390/molecules15031487
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author Obora, Yasushi
Ishii, Yasutaka
author_facet Obora, Yasushi
Ishii, Yasutaka
author_sort Obora, Yasushi
collection PubMed
description The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)(2)/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation.
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spelling pubmed-62572622018-12-04 Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins Obora, Yasushi Ishii, Yasutaka Molecules Review The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)(2)/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation. Molecular Diversity Preservation International 2010-03-09 /pmc/articles/PMC6257262/ /pubmed/20335996 http://dx.doi.org/10.3390/molecules15031487 Text en © 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Review
Obora, Yasushi
Ishii, Yasutaka
Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins
title Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins
title_full Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins
title_fullStr Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins
title_full_unstemmed Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins
title_short Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins
title_sort pd(ii)/hpmov-catalyzed direct oxidative coupling reaction of benzenes with olefins
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257262/
https://www.ncbi.nlm.nih.gov/pubmed/20335996
http://dx.doi.org/10.3390/molecules15031487
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