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Catalytic Asymmetric Nitro-Mannich Reactions with a Yb/K Heterobimetallic Catalyst

A catalytic asymmetric nitro-Mannich (aza-Henry) reaction with rare earth metal/alkali metal heterobimetallic catalysts is described. A Yb/K heterobimetallic catalyst assembled by an amide-based ligand promoted the asymmetric nitro-Mannich reaction to afford enantioenriched anti-β-nitroamines in up...

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Detalles Bibliográficos
Autores principales: Nitabaru, Tatsuya, Kumagai, Naoya, Shibasaki, Masakatsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257270/
https://www.ncbi.nlm.nih.gov/pubmed/20335980
http://dx.doi.org/10.3390/molecules15031280