Synthesis and Characterization of Organotin Containing Copolymers: Reactivity Ratio Studies

Organotin monomers containing dibutyltin groups – dibutyltin citraconate (DBTC) as a new monomer and dibutyltin maleate (DBTM) – were synthesized. Free radical copolymerizations of the organotin monomers with styrene (ST) and butyl acrylate (BA) were performed. The overall conversion was kept low (≤...

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Autores principales: Al-Deyab, Salem S., Al-Hazmi, Ali Mohsen, El-Newehy, Mohamed H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257311/
https://www.ncbi.nlm.nih.gov/pubmed/20336013
http://dx.doi.org/10.3390/molecules15031784
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author Al-Deyab, Salem S.
Al-Hazmi, Ali Mohsen
El-Newehy, Mohamed H.
author_facet Al-Deyab, Salem S.
Al-Hazmi, Ali Mohsen
El-Newehy, Mohamed H.
author_sort Al-Deyab, Salem S.
collection PubMed
description Organotin monomers containing dibutyltin groups – dibutyltin citraconate (DBTC) as a new monomer and dibutyltin maleate (DBTM) – were synthesized. Free radical copolymerizations of the organotin monomers with styrene (ST) and butyl acrylate (BA) were performed. The overall conversion was kept low (≤15% wt/wt) for all studied samples and the copolymers composition was determined from tin analysis using the Gillman and Rosenberg method. The reactivity ratios were calculated from the copolymer composition using the Fineman-Ross (FR) method. The synthesized monomers were characterized by elemental analysis, (1)H-, (13)C-NMR and FTIR spectroscopy.
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spelling pubmed-62573112018-12-04 Synthesis and Characterization of Organotin Containing Copolymers: Reactivity Ratio Studies Al-Deyab, Salem S. Al-Hazmi, Ali Mohsen El-Newehy, Mohamed H. Molecules Article Organotin monomers containing dibutyltin groups – dibutyltin citraconate (DBTC) as a new monomer and dibutyltin maleate (DBTM) – were synthesized. Free radical copolymerizations of the organotin monomers with styrene (ST) and butyl acrylate (BA) were performed. The overall conversion was kept low (≤15% wt/wt) for all studied samples and the copolymers composition was determined from tin analysis using the Gillman and Rosenberg method. The reactivity ratios were calculated from the copolymer composition using the Fineman-Ross (FR) method. The synthesized monomers were characterized by elemental analysis, (1)H-, (13)C-NMR and FTIR spectroscopy. Molecular Diversity Preservation International 2010-03-12 /pmc/articles/PMC6257311/ /pubmed/20336013 http://dx.doi.org/10.3390/molecules15031784 Text en © 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license ( (http://creativecommons.org/licenses/by/3.0/) http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Al-Deyab, Salem S.
Al-Hazmi, Ali Mohsen
El-Newehy, Mohamed H.
Synthesis and Characterization of Organotin Containing Copolymers: Reactivity Ratio Studies
title Synthesis and Characterization of Organotin Containing Copolymers: Reactivity Ratio Studies
title_full Synthesis and Characterization of Organotin Containing Copolymers: Reactivity Ratio Studies
title_fullStr Synthesis and Characterization of Organotin Containing Copolymers: Reactivity Ratio Studies
title_full_unstemmed Synthesis and Characterization of Organotin Containing Copolymers: Reactivity Ratio Studies
title_short Synthesis and Characterization of Organotin Containing Copolymers: Reactivity Ratio Studies
title_sort synthesis and characterization of organotin containing copolymers: reactivity ratio studies
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257311/
https://www.ncbi.nlm.nih.gov/pubmed/20336013
http://dx.doi.org/10.3390/molecules15031784
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