Novel Oxidative Ring Opening Reaction of 1H-Isotelluro-chromenes to Bis(o-formylstyryl) Ditellurides

The oxidation of 1-unsubstituted or 1-phenyl-1H-isotellurochromenes with m‑chloroperbenzoic acid (mCPBA) in CHCl(3) resulted in a ring opening reaction to produce as the sole products the corresponding o-formyl or benzoyl distyryl ditellurides, which were also produced by the hydrolysis of the 2-ben...

Descripción completa

Detalles Bibliográficos
Autores principales: Sashida, Haruki, Satoh, Hirohito, Ohyanagi, Kazuo, Kaname, Mamoru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257316/
https://www.ncbi.nlm.nih.gov/pubmed/20335994
http://dx.doi.org/10.3390/molecules15031466
Descripción
Sumario:The oxidation of 1-unsubstituted or 1-phenyl-1H-isotellurochromenes with m‑chloroperbenzoic acid (mCPBA) in CHCl(3) resulted in a ring opening reaction to produce as the sole products the corresponding o-formyl or benzoyl distyryl ditellurides, which were also produced by the hydrolysis of the 2-benzotelluropyrylium salts readily prepared from the parent isotellurochromene.

Ejemplares similares