Novel Oxidative Ring Opening Reaction of 1H-Isotelluro-chromenes to Bis(o-formylstyryl) Ditellurides

The oxidation of 1-unsubstituted or 1-phenyl-1H-isotellurochromenes with m‑chloroperbenzoic acid (mCPBA) in CHCl(3) resulted in a ring opening reaction to produce as the sole products the corresponding o-formyl or benzoyl distyryl ditellurides, which were also produced by the hydrolysis of the 2-ben...

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Autores principales: Sashida, Haruki, Satoh, Hirohito, Ohyanagi, Kazuo, Kaname, Mamoru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257316/
https://www.ncbi.nlm.nih.gov/pubmed/20335994
http://dx.doi.org/10.3390/molecules15031466
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author Sashida, Haruki
Satoh, Hirohito
Ohyanagi, Kazuo
Kaname, Mamoru
author_facet Sashida, Haruki
Satoh, Hirohito
Ohyanagi, Kazuo
Kaname, Mamoru
author_sort Sashida, Haruki
collection PubMed
description The oxidation of 1-unsubstituted or 1-phenyl-1H-isotellurochromenes with m‑chloroperbenzoic acid (mCPBA) in CHCl(3) resulted in a ring opening reaction to produce as the sole products the corresponding o-formyl or benzoyl distyryl ditellurides, which were also produced by the hydrolysis of the 2-benzotelluropyrylium salts readily prepared from the parent isotellurochromene.
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spelling pubmed-62573162018-12-04 Novel Oxidative Ring Opening Reaction of 1H-Isotelluro-chromenes to Bis(o-formylstyryl) Ditellurides Sashida, Haruki Satoh, Hirohito Ohyanagi, Kazuo Kaname, Mamoru Molecules Article The oxidation of 1-unsubstituted or 1-phenyl-1H-isotellurochromenes with m‑chloroperbenzoic acid (mCPBA) in CHCl(3) resulted in a ring opening reaction to produce as the sole products the corresponding o-formyl or benzoyl distyryl ditellurides, which were also produced by the hydrolysis of the 2-benzotelluropyrylium salts readily prepared from the parent isotellurochromene. Molecular Diversity Preservation International 2010-03-09 /pmc/articles/PMC6257316/ /pubmed/20335994 http://dx.doi.org/10.3390/molecules15031466 Text en © 2010 by the authors; http://creativecommons.org/licenses/by/3.0/ licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Sashida, Haruki
Satoh, Hirohito
Ohyanagi, Kazuo
Kaname, Mamoru
Novel Oxidative Ring Opening Reaction of 1H-Isotelluro-chromenes to Bis(o-formylstyryl) Ditellurides
title Novel Oxidative Ring Opening Reaction of 1H-Isotelluro-chromenes to Bis(o-formylstyryl) Ditellurides
title_full Novel Oxidative Ring Opening Reaction of 1H-Isotelluro-chromenes to Bis(o-formylstyryl) Ditellurides
title_fullStr Novel Oxidative Ring Opening Reaction of 1H-Isotelluro-chromenes to Bis(o-formylstyryl) Ditellurides
title_full_unstemmed Novel Oxidative Ring Opening Reaction of 1H-Isotelluro-chromenes to Bis(o-formylstyryl) Ditellurides
title_short Novel Oxidative Ring Opening Reaction of 1H-Isotelluro-chromenes to Bis(o-formylstyryl) Ditellurides
title_sort novel oxidative ring opening reaction of 1h-isotelluro-chromenes to bis(o-formylstyryl) ditellurides
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257316/
https://www.ncbi.nlm.nih.gov/pubmed/20335994
http://dx.doi.org/10.3390/molecules15031466
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