Influence of Solvent, Electron Acceptors and Arenes on Photochemical Decarboxylation of Free Carboxylic Acids via Single Electron Transfer (SET)

Single electron transfer (SET)-photochemical decarboxylation of free carboxylic acids was performed in a polar solvent using several arenes such as phenanthrene, naphthalene, 1-methylnaphthalene, biphenyl, triphenylene, and chrysene in the presence of various electron acceptors such as 1,2-, 1,3-, a...

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Autores principales: Yoshimi, Yasuharu, Hayashi, Shota, Nishikawa, Keisuke, Haga, Yoshiki, Maeda, Kousuke, Morita, Toshio, Itou, Tatsuya, Okada, Yutaka, Ichinose, Nobuyuki, Hatanaka, Minoru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257324/
https://www.ncbi.nlm.nih.gov/pubmed/20428069
http://dx.doi.org/10.3390/molecules15042623
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author Yoshimi, Yasuharu
Hayashi, Shota
Nishikawa, Keisuke
Haga, Yoshiki
Maeda, Kousuke
Morita, Toshio
Itou, Tatsuya
Okada, Yutaka
Ichinose, Nobuyuki
Hatanaka, Minoru
author_facet Yoshimi, Yasuharu
Hayashi, Shota
Nishikawa, Keisuke
Haga, Yoshiki
Maeda, Kousuke
Morita, Toshio
Itou, Tatsuya
Okada, Yutaka
Ichinose, Nobuyuki
Hatanaka, Minoru
author_sort Yoshimi, Yasuharu
collection PubMed
description Single electron transfer (SET)-photochemical decarboxylation of free carboxylic acids was performed in a polar solvent using several arenes such as phenanthrene, naphthalene, 1-methylnaphthalene, biphenyl, triphenylene, and chrysene in the presence of various electron acceptors such as 1,2-, 1,3-, and 1,4-dicyanobenzenes, methyl 4-cyanobenzoate, and 1,4-dicyanonaphthalene. The decarboxylation reaction was influenced by the arenes, electron acceptors, and solvent. The best result was achieved by the photoreaction using biphenyl and 1,4-dicyanonaphthalene in aqueous acetonitrile.
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spelling pubmed-62573242018-11-30 Influence of Solvent, Electron Acceptors and Arenes on Photochemical Decarboxylation of Free Carboxylic Acids via Single Electron Transfer (SET) Yoshimi, Yasuharu Hayashi, Shota Nishikawa, Keisuke Haga, Yoshiki Maeda, Kousuke Morita, Toshio Itou, Tatsuya Okada, Yutaka Ichinose, Nobuyuki Hatanaka, Minoru Molecules Article Single electron transfer (SET)-photochemical decarboxylation of free carboxylic acids was performed in a polar solvent using several arenes such as phenanthrene, naphthalene, 1-methylnaphthalene, biphenyl, triphenylene, and chrysene in the presence of various electron acceptors such as 1,2-, 1,3-, and 1,4-dicyanobenzenes, methyl 4-cyanobenzoate, and 1,4-dicyanonaphthalene. The decarboxylation reaction was influenced by the arenes, electron acceptors, and solvent. The best result was achieved by the photoreaction using biphenyl and 1,4-dicyanonaphthalene in aqueous acetonitrile. Molecular Diversity Preservation International 2010-04-12 /pmc/articles/PMC6257324/ /pubmed/20428069 http://dx.doi.org/10.3390/molecules15042623 Text en © 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Yoshimi, Yasuharu
Hayashi, Shota
Nishikawa, Keisuke
Haga, Yoshiki
Maeda, Kousuke
Morita, Toshio
Itou, Tatsuya
Okada, Yutaka
Ichinose, Nobuyuki
Hatanaka, Minoru
Influence of Solvent, Electron Acceptors and Arenes on Photochemical Decarboxylation of Free Carboxylic Acids via Single Electron Transfer (SET)
title Influence of Solvent, Electron Acceptors and Arenes on Photochemical Decarboxylation of Free Carboxylic Acids via Single Electron Transfer (SET)
title_full Influence of Solvent, Electron Acceptors and Arenes on Photochemical Decarboxylation of Free Carboxylic Acids via Single Electron Transfer (SET)
title_fullStr Influence of Solvent, Electron Acceptors and Arenes on Photochemical Decarboxylation of Free Carboxylic Acids via Single Electron Transfer (SET)
title_full_unstemmed Influence of Solvent, Electron Acceptors and Arenes on Photochemical Decarboxylation of Free Carboxylic Acids via Single Electron Transfer (SET)
title_short Influence of Solvent, Electron Acceptors and Arenes on Photochemical Decarboxylation of Free Carboxylic Acids via Single Electron Transfer (SET)
title_sort influence of solvent, electron acceptors and arenes on photochemical decarboxylation of free carboxylic acids via single electron transfer (set)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257324/
https://www.ncbi.nlm.nih.gov/pubmed/20428069
http://dx.doi.org/10.3390/molecules15042623
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