Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior

Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the sy...

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Detalles Bibliográficos
Autores principales: Morales-Espinoza, Eric G., Sanchez-Montes, Karla E., Klimova, Elena, Klimova, Tatiana, Lijanova, Irina V., Maldonado, José L., Ramos-Ortíz, Gabriel, Hernández-Ortega, Simón, Martínez-García, Marcos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257368/
https://www.ncbi.nlm.nih.gov/pubmed/20428064
http://dx.doi.org/10.3390/molecules15042564
Descripción
Sumario:Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the synthesized dendrimers was confirmed by (1)H- and (13)C-NMR, electrospray mass spectrometry and elemental analysis. Cubic non-linear optical behavior of the ferrocene and porphyrin-containing dendrimers was studied in solid thin films by THG Maker-Fringe technique at 1,260 nm.

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