Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior

Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the sy...

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Autores principales: Morales-Espinoza, Eric G., Sanchez-Montes, Karla E., Klimova, Elena, Klimova, Tatiana, Lijanova, Irina V., Maldonado, José L., Ramos-Ortíz, Gabriel, Hernández-Ortega, Simón, Martínez-García, Marcos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257368/
https://www.ncbi.nlm.nih.gov/pubmed/20428064
http://dx.doi.org/10.3390/molecules15042564
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author Morales-Espinoza, Eric G.
Sanchez-Montes, Karla E.
Klimova, Elena
Klimova, Tatiana
Lijanova, Irina V.
Maldonado, José L.
Ramos-Ortíz, Gabriel
Hernández-Ortega, Simón
Martínez-García, Marcos
author_facet Morales-Espinoza, Eric G.
Sanchez-Montes, Karla E.
Klimova, Elena
Klimova, Tatiana
Lijanova, Irina V.
Maldonado, José L.
Ramos-Ortíz, Gabriel
Hernández-Ortega, Simón
Martínez-García, Marcos
author_sort Morales-Espinoza, Eric G.
collection PubMed
description Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the synthesized dendrimers was confirmed by (1)H- and (13)C-NMR, electrospray mass spectrometry and elemental analysis. Cubic non-linear optical behavior of the ferrocene and porphyrin-containing dendrimers was studied in solid thin films by THG Maker-Fringe technique at 1,260 nm.
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spelling pubmed-62573682018-11-30 Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior Morales-Espinoza, Eric G. Sanchez-Montes, Karla E. Klimova, Elena Klimova, Tatiana Lijanova, Irina V. Maldonado, José L. Ramos-Ortíz, Gabriel Hernández-Ortega, Simón Martínez-García, Marcos Molecules Article Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the synthesized dendrimers was confirmed by (1)H- and (13)C-NMR, electrospray mass spectrometry and elemental analysis. Cubic non-linear optical behavior of the ferrocene and porphyrin-containing dendrimers was studied in solid thin films by THG Maker-Fringe technique at 1,260 nm. Molecular Diversity Preservation International 2010-04-12 /pmc/articles/PMC6257368/ /pubmed/20428064 http://dx.doi.org/10.3390/molecules15042564 Text en © 2010 by the authors; http://creativecommons.org/licenses/by/3.0/ licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Morales-Espinoza, Eric G.
Sanchez-Montes, Karla E.
Klimova, Elena
Klimova, Tatiana
Lijanova, Irina V.
Maldonado, José L.
Ramos-Ortíz, Gabriel
Hernández-Ortega, Simón
Martínez-García, Marcos
Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior
title Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior
title_full Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior
title_fullStr Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior
title_full_unstemmed Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior
title_short Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior
title_sort dendrimers containing ferrocene and porphyrin moieties: synthesis and cubic non-linear optical behavior
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257368/
https://www.ncbi.nlm.nih.gov/pubmed/20428064
http://dx.doi.org/10.3390/molecules15042564
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