Cargando…

Enhanced Reactivity of [Hydroxy(tosyloxy)iodo]benzene in Fluoroalcohol Media. Efficient Direct Synthesis of Thienyl(aryl)iodonium Salts

In this manuscript, we report clear evidence for the generation of aromatic cation radicals produced by using [hydroxy(tosyloxy)iodo]benzene (HTIB) in fluoroalcohol solvents such as 2,2,2-trifluoroethanol (TFE) and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP). The single-electron-transfer (SET) oxidatio...

Descripción completa

Detalles Bibliográficos
Autores principales:	Ito, Motoki, Ogawa, Chieko, Yamaoka, Nobutaka, Fujioka, Hiromichi, Dohi, Toshifumi, Kita, Yasuyuki
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Molecular Diversity Preservation International 2010
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257409/ https://www.ncbi.nlm.nih.gov/pubmed/20336022 http://dx.doi.org/10.3390/molecules15031918

Ejemplares similares

Nucleophilic Arylation of Halopurines Facilitated by Brønsted Acid in Fluoroalcohol
por: Takenaga, Naoko, et al.
Publicado: (2019)

Application of [Hydroxy(tosyloxy)iodo]benzene in the Wittig-Ring Expansion Sequence for the Synthesis of β‑Benzocyclo-alkenones from α-Benzocycloalkenones
por: Justik, Michael W., et al.
Publicado: (2005)

Imide arylation with aryl(TMP)iodonium tosylates
por: Basu, Souradeep, et al.
Publicado: (2018)

Synthesis of Multifunctional Aryl(trifloxyalkenyl)iodonium Triflate Salts
por: Tóth, Balázs L., et al.
Publicado: (2019)

Dataset on synthesis and crystallographic structure of phenyl(TMP)iodonium(III) acetate
por: China, Hideyasu, et al.
Publicado: (2019)

Synthesis of No-Carrier-Added 4-[(18)F]Fluorophenol from 4-Benzyloxyphenyl-(2-thienyl)iodonium Bromide
por: Ross, Tobias L., et al.
Publicado: (2011)

1,8-Bis(tosyloxy)-9,10-anthraquinone
por: Niedziałkowski, Paweł, et al.
Publicado: (2009)

Synthesis of Uracil-Iodonium(III) Salts for Practical Utilization as Nucleobase Synthetic Modules
por: Takenaga, Naoko, et al.
Publicado: (2019)

Copper-Catalyzed [(18)F]Fluorination of (Mesityl)(aryl)iodonium Salts
por: Ichiishi, Naoko, et al.
Publicado: (2014)

Living/Controlled Anionic Polymerization of Glycolide in Fluoroalcohols: Toward Sustainable Bioplastics
por: Zhang, Pengfei, et al.
Publicado: (2023)

Electrochemical selenium- and iodonium-initiated cyclisation of hydroxy-functionalised 1,4-dienes
por: Röse, Philipp, et al.
Publicado: (2015)

Sodium 2-iodobenzenesulfonate monohydrate
por: Arshad, Muhammad Nadeem, et al.
Publicado: (2008)

2-Iodo-1,3-dimethoxybenzene
por: Xue, Li-Ping, et al.
Publicado: (2009)

Potassium 2-iodobenzenesulfonate monohydrate
por: Arshad, Muhammad Nadeem, et al.
Publicado: (2008)

N′-[(E)-2-Hydroxy-5-iodobenzylidene]-4-methylbenzenesulfonohydrazide
por: Ghorbanloo, Massomeh, et al.
Publicado: (2012)

9-Ethyl-3,6-bis(5-iodo-2-thienyl)-9H-carbazole
por: Xu, Guo-Yi, et al.
Publicado: (2010)

4-Chloro-1-iodo-2-nitrobenzene
por: Tahir, M. Nawaz, et al.
Publicado: (2009)

1,4-Bis(iodomethyl)benzene
por: McAdam, C. John, et al.
Publicado: (2009)

(Phenyliodosyl)benzene tosylate dihydrate
por: Smith, Timothy J., et al.
Publicado: (2022)

1-Iodo-4-methoxy-2-nitrobenzene
por: Wardell, James L., et al.
Publicado: (2012)

4-(2-Iodobenzenesulfonamido)benzoic acid monohydrate
por: Arshad, Muhammad Nadeem, et al.
Publicado: (2009)

2-Bromo-5-iodo-1,3-dimethylbenzene
por: Liu, Rui, et al.
Publicado: (2007)

5-Bromo-2-iodo-1,3-dimethylbenzene
por: Liu, Rui, et al.
Publicado: (2007)

RAFT Polymerization of Styrene and Maleimide in the Presence of Fluoroalcohol: Hydrogen Bonding Effects with Classical Alternating Copolymerization as Reference
por: Yao, Fangjun, et al.
Publicado: (2017)

Hypervalent iodine-guided electrophilic substitution: para-selective substitution across aryl iodonium compounds with benzyl groups
por: Mowdawalla, Cyrus, et al.
Publicado: (2018)

1,2-Bis(2-methyl-5-phenyl-3-thienyl)benzene
por: Miao, Wen-Juan, et al.
Publicado: (2009)

2-Chloro-4-(2-iodobenzenesulfonamido)benzoic acid
por: Arshad, Muhammad Nadeem, et al.
Publicado: (2011)

N-(2-Iodophenyl)benzenecarboximidamide
por: Zhang, Yin-jun, et al.
Publicado: (2012)

2-Chloro-5-(2-iodobenzenesulfonamido)benzoic acid
por: Arshad, Muhammad Nadeem, et al.
Publicado: (2009)

2,4-Dichloro-1-iodo-6-nitrobenzene
por: Li, Xueshu, et al.
Publicado: (2014)

(5-Fluoro-4′-methylbiphenyl-3-yl)(2,4,6-trimethylphenyl)iodonium trifluoromethanesulfonate
por: Shao, Ying, et al.
Publicado: (2014)

Isolation and Reactivity of Trifluoromethyl Iodonium Salts
por: Brantley, Johnathan N., et al.
Publicado: (2016)

5-tert-Butyl-2-hydroxy-3-(2-thienyl)benzaldehyde
por: Wang, Yanwei, et al.
Publicado: (2010)

New 3-Aryl-2-(2-thienyl)acrylonitriles with High Activity Against Hepatoma Cells
por: Schaller, Eva, et al.
Publicado: (2021)

Halogen Bonding Helicates Encompassing Iodonium Cations
por: Vanderkooy, Alan, et al.
Publicado: (2019)

3-Hydroxy-N′-[(E)-2-thienylmethylidene]-2-naphthohydrazide
por: Wu, Qingkun, et al.
Publicado: (2011)

1-[4-(Iodomethyl)cyclohexyl]-4-methylbenzene
por: Wang, Juan, et al.
Publicado: (2011)

(E)-2-(2-Hydroxy-5-iodobenzylidene)hydrazinecarboxamide
por: Bikas, Rahman, et al.
Publicado: (2012)

[3-Methoxy-5-(methoxycarbonyl)isoxazol-4-yl](4-methoxyphenyl)iodonium 2,2,2-trifluoroacetate
por: Abdul Manan, Mohd Abdul Fatah, et al.
Publicado: (2023)

(E)-4-Hydroxy-N′-(2-hydroxy-5-iodobenzylidene)benzohydrazide methanol monosolvate
por: Mahboubi Anarjan, Parisa, et al.
Publicado: (2012)

Cannot write session to /tmp/vufind_sessions/sess_h85kne86ila73er3rjdgt3klh9