Synthesis, Characterization and Reactivity Ratio Study of Poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole)

The organotin monomer di(tri-n-butyltin) citraconate (DTBTC, I) was synthesized. Subsequently this monomer was copolymerized with N-vinylimidazole (VI) using a free radical technique. The overall conversion was kept low (≤14% wt/wt) for all studied samples and the copolymer composition was determine...

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Autores principales: Al-Deyab, Salem S., El-Newehy, Mohamed H., Al-Hazmi, Ali M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257635/
https://www.ncbi.nlm.nih.gov/pubmed/20657390
http://dx.doi.org/10.3390/molecules15074750
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author Al-Deyab, Salem S.
El-Newehy, Mohamed H.
Al-Hazmi, Ali M.
author_facet Al-Deyab, Salem S.
El-Newehy, Mohamed H.
Al-Hazmi, Ali M.
author_sort Al-Deyab, Salem S.
collection PubMed
description The organotin monomer di(tri-n-butyltin) citraconate (DTBTC, I) was synthesized. Subsequently this monomer was copolymerized with N-vinylimidazole (VI) using a free radical technique. The overall conversion was kept low (≤14% wt/wt) for all studied samples and the copolymer composition was determined from tin analysis using the Gilman and Rosenberg method. The synthesized monomer and copolymer were further characterized by elemental analysis, (1)H- and (13)C-NMR, and FTIR spectroscopy.
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spelling pubmed-62576352018-12-06 Synthesis, Characterization and Reactivity Ratio Study of Poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole) Al-Deyab, Salem S. El-Newehy, Mohamed H. Al-Hazmi, Ali M. Molecules Article The organotin monomer di(tri-n-butyltin) citraconate (DTBTC, I) was synthesized. Subsequently this monomer was copolymerized with N-vinylimidazole (VI) using a free radical technique. The overall conversion was kept low (≤14% wt/wt) for all studied samples and the copolymer composition was determined from tin analysis using the Gilman and Rosenberg method. The synthesized monomer and copolymer were further characterized by elemental analysis, (1)H- and (13)C-NMR, and FTIR spectroscopy. MDPI 2010-07-07 /pmc/articles/PMC6257635/ /pubmed/20657390 http://dx.doi.org/10.3390/molecules15074750 Text en © 2010 by the authors; http://creativecommons.org/licenses/by/3.0/ licensee MDPI, Basel, Switzerland. This article is an Open Access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Al-Deyab, Salem S.
El-Newehy, Mohamed H.
Al-Hazmi, Ali M.
Synthesis, Characterization and Reactivity Ratio Study of Poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole)
title Synthesis, Characterization and Reactivity Ratio Study of Poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole)
title_full Synthesis, Characterization and Reactivity Ratio Study of Poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole)
title_fullStr Synthesis, Characterization and Reactivity Ratio Study of Poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole)
title_full_unstemmed Synthesis, Characterization and Reactivity Ratio Study of Poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole)
title_short Synthesis, Characterization and Reactivity Ratio Study of Poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole)
title_sort synthesis, characterization and reactivity ratio study of poly(di(tri-n-butyltin) citraconate-co-n-vinylimidazole)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6257635/
https://www.ncbi.nlm.nih.gov/pubmed/20657390
http://dx.doi.org/10.3390/molecules15074750
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