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Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO

Enamine and imine represent two of the most common reaction intermediates in syntheses, and the imine intermediates containing α-hydrogen often exhibit the similar reactivity to enamines due to their rapid tautomerization to enamine tautomers. Herein, we report that the minor structural difference b...

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Detalles Bibliográficos
Autores principales: Jie, Xiaoming, Shang, Yaping, Chen, Zhe-Ning, Zhang, Xiaofeng, Zhuang, Wei, Su, Weiping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6258700/
https://www.ncbi.nlm.nih.gov/pubmed/30479335
http://dx.doi.org/10.1038/s41467-018-07534-x