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The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose †

The synthesis of new α,β-unsaturated furanuronic acid derivatives of α-gluco- (3), β-gluco- (6) and β-manno-chloraloses (9) via a convenient one pot procedure using the Knoevenagel-Doebner reaction approach are described. The dialdofuranose derivatives were reacted with malonic acid under Knoevenage...

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Detalles Bibliográficos
Autores principales: Kök, Gökhan, Karayıldırım, Tamer, Ay, Kadir, Ay, Emriye
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6259183/
https://www.ncbi.nlm.nih.gov/pubmed/21042261
http://dx.doi.org/10.3390/molecules15117724
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author Kök, Gökhan
Karayıldırım, Tamer
Ay, Kadir
Ay, Emriye
author_facet Kök, Gökhan
Karayıldırım, Tamer
Ay, Kadir
Ay, Emriye
author_sort Kök, Gökhan
collection PubMed
description The synthesis of new α,β-unsaturated furanuronic acid derivatives of α-gluco- (3), β-gluco- (6) and β-manno-chloraloses (9) via a convenient one pot procedure using the Knoevenagel-Doebner reaction approach are described. The dialdofuranose derivatives were reacted with malonic acid under Knoevenagel-Doebner reaction conditions and (E)-α,β-unsaturated furanuronic acid derivatives were obtained.
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spelling pubmed-62591832018-12-06 The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose † Kök, Gökhan Karayıldırım, Tamer Ay, Kadir Ay, Emriye Molecules Article The synthesis of new α,β-unsaturated furanuronic acid derivatives of α-gluco- (3), β-gluco- (6) and β-manno-chloraloses (9) via a convenient one pot procedure using the Knoevenagel-Doebner reaction approach are described. The dialdofuranose derivatives were reacted with malonic acid under Knoevenagel-Doebner reaction conditions and (E)-α,β-unsaturated furanuronic acid derivatives were obtained. MDPI 2010-10-29 /pmc/articles/PMC6259183/ /pubmed/21042261 http://dx.doi.org/10.3390/molecules15117724 Text en © 2010 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Kök, Gökhan
Karayıldırım, Tamer
Ay, Kadir
Ay, Emriye
The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose †
title The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose †
title_full The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose †
title_fullStr The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose †
title_full_unstemmed The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose †
title_short The Knoevenagel-Doebner Reaction on 1,2-O-(2,2,2-Trichloroethylidene) Derivatives of D-Gluco- and D-Manno- furanose †
title_sort knoevenagel-doebner reaction on 1,2-o-(2,2,2-trichloroethylidene) derivatives of d-gluco- and d-manno- furanose †
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6259183/
https://www.ncbi.nlm.nih.gov/pubmed/21042261
http://dx.doi.org/10.3390/molecules15117724
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