Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl(2)/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)

The propensity of a half-sandwich (η5-tetramethylcyclopentadienyl)dimethylsilylamido Ti(IV)-based catalyst bearing an auxiliary diethylboryl-protected pyridyl moiety (Ti-8), activated by methylaluminoxane (MAO) to homopolymerize α-olefins such as ethylene, 1-hexene and styrene as well as to copolyme...

Descripción completa

Detalles Bibliográficos
Autores principales: Camadanli, Sebnem, Decker, Ulrich, Kühnel, Christa, Reinhardt, Ingrid, Buchmeiser, Michael R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6259193/
https://www.ncbi.nlm.nih.gov/pubmed/21240147
http://dx.doi.org/10.3390/molecules16010567
_version_ 1783374630317195264
author Camadanli, Sebnem
Decker, Ulrich
Kühnel, Christa
Reinhardt, Ingrid
Buchmeiser, Michael R.
author_facet Camadanli, Sebnem
Decker, Ulrich
Kühnel, Christa
Reinhardt, Ingrid
Buchmeiser, Michael R.
author_sort Camadanli, Sebnem
collection PubMed
description The propensity of a half-sandwich (η5-tetramethylcyclopentadienyl)dimethylsilylamido Ti(IV)-based catalyst bearing an auxiliary diethylboryl-protected pyridyl moiety (Ti-8), activated by methylaluminoxane (MAO) to homopolymerize α-olefins such as ethylene, 1-hexene and styrene as well as to copolymerize styrene with 1,3-cyclo-hexadiene is described. The reactivity of Ti-8 was investigated in comparison to a 6-(2-(diethylboryl)phenyl)pyrid-2-yl-free analogue (Ti-3).
format Online
Article
Text
id pubmed-6259193
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-62591932018-12-07 Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl(2)/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl) Camadanli, Sebnem Decker, Ulrich Kühnel, Christa Reinhardt, Ingrid Buchmeiser, Michael R. Molecules Article The propensity of a half-sandwich (η5-tetramethylcyclopentadienyl)dimethylsilylamido Ti(IV)-based catalyst bearing an auxiliary diethylboryl-protected pyridyl moiety (Ti-8), activated by methylaluminoxane (MAO) to homopolymerize α-olefins such as ethylene, 1-hexene and styrene as well as to copolymerize styrene with 1,3-cyclo-hexadiene is described. The reactivity of Ti-8 was investigated in comparison to a 6-(2-(diethylboryl)phenyl)pyrid-2-yl-free analogue (Ti-3). MDPI 2011-01-14 /pmc/articles/PMC6259193/ /pubmed/21240147 http://dx.doi.org/10.3390/molecules16010567 Text en © 2011 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Camadanli, Sebnem
Decker, Ulrich
Kühnel, Christa
Reinhardt, Ingrid
Buchmeiser, Michael R.
Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl(2)/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)
title Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl(2)/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)
title_full Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl(2)/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)
title_fullStr Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl(2)/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)
title_full_unstemmed Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl(2)/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)
title_short Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl(2)/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)
title_sort homopolymerization of ethylene, 1-hexene, styrene and copolymerization of styrene with 1,3-cyclohexadiene using (η(5)-tetramethylcyclopentadienyl)dimethylsilyl(n-ar’)amido-ticl(2)/mao (ar’=6-(2-(diethylboryl)phenyl)pyrid-2-yl, biphen-3-yl)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6259193/
https://www.ncbi.nlm.nih.gov/pubmed/21240147
http://dx.doi.org/10.3390/molecules16010567
work_keys_str_mv AT camadanlisebnem homopolymerizationofethylene1hexenestyreneandcopolymerizationofstyrenewith13cyclohexadieneusingē5tetramethylcyclopentadienyldimethylsilylnaramidoticl2maoar62diethylborylphenylpyrid2ylbiphen3yl
AT deckerulrich homopolymerizationofethylene1hexenestyreneandcopolymerizationofstyrenewith13cyclohexadieneusingē5tetramethylcyclopentadienyldimethylsilylnaramidoticl2maoar62diethylborylphenylpyrid2ylbiphen3yl
AT kuhnelchrista homopolymerizationofethylene1hexenestyreneandcopolymerizationofstyrenewith13cyclohexadieneusingē5tetramethylcyclopentadienyldimethylsilylnaramidoticl2maoar62diethylborylphenylpyrid2ylbiphen3yl
AT reinhardtingrid homopolymerizationofethylene1hexenestyreneandcopolymerizationofstyrenewith13cyclohexadieneusingē5tetramethylcyclopentadienyldimethylsilylnaramidoticl2maoar62diethylborylphenylpyrid2ylbiphen3yl
AT buchmeisermichaelr homopolymerizationofethylene1hexenestyreneandcopolymerizationofstyrenewith13cyclohexadieneusingē5tetramethylcyclopentadienyldimethylsilylnaramidoticl2maoar62diethylborylphenylpyrid2ylbiphen3yl

Ejemplares similares