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Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (η(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl(2)/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)
The propensity of a half-sandwich (η5-tetramethylcyclopentadienyl)dimethylsilylamido Ti(IV)-based catalyst bearing an auxiliary diethylboryl-protected pyridyl moiety (Ti-8), activated by methylaluminoxane (MAO) to homopolymerize α-olefins such as ethylene, 1-hexene and styrene as well as to copolyme...
Autores principales: | Camadanli, Sebnem, Decker, Ulrich, Kühnel, Christa, Reinhardt, Ingrid, Buchmeiser, Michael R. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6259193/ https://www.ncbi.nlm.nih.gov/pubmed/21240147 http://dx.doi.org/10.3390/molecules16010567 |
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