Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands

An efficient and stereoselective catalytic system for the Heck cross coupling reaction using novel 1,3-dialkyl-3,4,5,6-tetrahydropyrimidinium salts (1, LHX) and Pd(OAc)(2) loading has been reported. The palladium complexes derived from the salts 1a-f prepared in situ exhibit good catalytic activity...

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Detalles Bibliográficos
Autores principales: Yaşar, Sedat, Özcan, Emine Özge, Gürbüz, Nevin, Çetinkaya, Bekir, Özdemir, İsmail
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6263193/
https://www.ncbi.nlm.nih.gov/pubmed/20335935
http://dx.doi.org/10.3390/molecules15020649
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author Yaşar, Sedat
Özcan, Emine Özge
Gürbüz, Nevin
Çetinkaya, Bekir
Özdemir, İsmail
author_facet Yaşar, Sedat
Özcan, Emine Özge
Gürbüz, Nevin
Çetinkaya, Bekir
Özdemir, İsmail
author_sort Yaşar, Sedat
collection PubMed
description An efficient and stereoselective catalytic system for the Heck cross coupling reaction using novel 1,3-dialkyl-3,4,5,6-tetrahydropyrimidinium salts (1, LHX) and Pd(OAc)(2) loading has been reported. The palladium complexes derived from the salts 1a-f prepared in situ exhibit good catalytic activity in the Heck coupling reaction of aryl bromides under mild conditions.
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spelling pubmed-62631932018-12-03 Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands Yaşar, Sedat Özcan, Emine Özge Gürbüz, Nevin Çetinkaya, Bekir Özdemir, İsmail Molecules Article An efficient and stereoselective catalytic system for the Heck cross coupling reaction using novel 1,3-dialkyl-3,4,5,6-tetrahydropyrimidinium salts (1, LHX) and Pd(OAc)(2) loading has been reported. The palladium complexes derived from the salts 1a-f prepared in situ exhibit good catalytic activity in the Heck coupling reaction of aryl bromides under mild conditions. Molecular Diversity Preservation International 2010-01-28 /pmc/articles/PMC6263193/ /pubmed/20335935 http://dx.doi.org/10.3390/molecules15020649 Text en © 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Yaşar, Sedat
Özcan, Emine Özge
Gürbüz, Nevin
Çetinkaya, Bekir
Özdemir, İsmail
Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands
title Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands
title_full Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands
title_fullStr Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands
title_full_unstemmed Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands
title_short Palladium-Catalyzed Heck Coupling Reaction of Aryl Bromides in Aqueous Media Using Tetrahydropyrimidinium Salts as Carbene Ligands
title_sort palladium-catalyzed heck coupling reaction of aryl bromides in aqueous media using tetrahydropyrimidinium salts as carbene ligands
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6263193/
https://www.ncbi.nlm.nih.gov/pubmed/20335935
http://dx.doi.org/10.3390/molecules15020649
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