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Synthesis of Endohedral Metallofullerene Glycoconjugates by Carbene Addition

Endohedral metallofullerene glycoconjugates were synthesized under mild conditions by carbene addition using appropriate glycosylidene-derived diazirine with La(2)@I(h)-C(80). NMR spectroscopic studies revealed that the glycoconjugate consists of two diastereomers of [6,6]-open mono-adducts. The ele...

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Detalles Bibliográficos
Autores principales: Yamada, Michio, Someya, Chika I., Nakahodo, Tsukasa, Maeda, Yutaka, Tsuchiya, Takahiro, Akasaka, Takeshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264206/
https://www.ncbi.nlm.nih.gov/pubmed/22083236
http://dx.doi.org/10.3390/molecules16119495