Synthesis of New Pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions

A comparison was made of the effectiveness of the functionalization reactions of pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) using sulphated zirconia in protection-deprotection reactions and Mg/Al hydrotalcite in a cyanosilylation reaction, under classical thermal conditions and...

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Autores principales: Guerra-Navarro, Nahí Adriana, Palacios-Grijalva, Laura Nadxieli, Angeles-Beltrán, Deyanira, Negrón-Silva, Guillermo E., Lomas-Romero, Leticia, González-Zamora, Eduardo, Gaviño-Ramírez, Rubén, Navarrete-Bolaños, Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264255/
https://www.ncbi.nlm.nih.gov/pubmed/21818059
http://dx.doi.org/10.3390/molecules16086561
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author Guerra-Navarro, Nahí Adriana
Palacios-Grijalva, Laura Nadxieli
Angeles-Beltrán, Deyanira
Negrón-Silva, Guillermo E.
Lomas-Romero, Leticia
González-Zamora, Eduardo
Gaviño-Ramírez, Rubén
Navarrete-Bolaños, Juan
author_facet Guerra-Navarro, Nahí Adriana
Palacios-Grijalva, Laura Nadxieli
Angeles-Beltrán, Deyanira
Negrón-Silva, Guillermo E.
Lomas-Romero, Leticia
González-Zamora, Eduardo
Gaviño-Ramírez, Rubén
Navarrete-Bolaños, Juan
author_sort Guerra-Navarro, Nahí Adriana
collection PubMed
description A comparison was made of the effectiveness of the functionalization reactions of pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) using sulphated zirconia in protection-deprotection reactions and Mg/Al hydrotalcite in a cyanosilylation reaction, under classical thermal conditions and imposing microwave radiation; improved yields and reaction times were considered.
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spelling pubmed-62642552018-12-10 Synthesis of New Pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions Guerra-Navarro, Nahí Adriana Palacios-Grijalva, Laura Nadxieli Angeles-Beltrán, Deyanira Negrón-Silva, Guillermo E. Lomas-Romero, Leticia González-Zamora, Eduardo Gaviño-Ramírez, Rubén Navarrete-Bolaños, Juan Molecules Article A comparison was made of the effectiveness of the functionalization reactions of pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) using sulphated zirconia in protection-deprotection reactions and Mg/Al hydrotalcite in a cyanosilylation reaction, under classical thermal conditions and imposing microwave radiation; improved yields and reaction times were considered. MDPI 2011-08-04 /pmc/articles/PMC6264255/ /pubmed/21818059 http://dx.doi.org/10.3390/molecules16086561 Text en © 2011 by the authors; https://creativecommons.org/licenses/by/3.0/licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/ (https://creativecommons.org/licenses/by/3.0/) ).
spellingShingle Article
Guerra-Navarro, Nahí Adriana
Palacios-Grijalva, Laura Nadxieli
Angeles-Beltrán, Deyanira
Negrón-Silva, Guillermo E.
Lomas-Romero, Leticia
González-Zamora, Eduardo
Gaviño-Ramírez, Rubén
Navarrete-Bolaños, Juan
Synthesis of New Pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions
title Synthesis of New Pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions
title_full Synthesis of New Pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions
title_fullStr Synthesis of New Pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions
title_full_unstemmed Synthesis of New Pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions
title_short Synthesis of New Pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions
title_sort synthesis of new pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane-8,11-dione (pcu) cyanosilylated derivatives using sulphated zirconia and hydrotalcite as catalysts in microwave-assisted reactions under solvent free conditions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264255/
https://www.ncbi.nlm.nih.gov/pubmed/21818059
http://dx.doi.org/10.3390/molecules16086561
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