Synthesis of [(4-Chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines

The reactions of 2-, 3- and 4-aminopyridines with 4,5-dichloro-1,2,3-dithiazol-ium chloride (Appel salt) 4 to give N-(4-chloro-5H-1,2,3-dithiazol-5-ylidene)pyridin-X-amines 1a (X = 2), 1g (X = 3) and 1k (X = 4) were optimized with respect to base, temperature and reaction time. Based on these condit...

Descripción completa

Detalles Bibliográficos
Autores principales: Koutentis, Panayiotis A., Koyioni, Maria, Michaelidou, Sophia S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264322/
https://www.ncbi.nlm.nih.gov/pubmed/22442824
http://dx.doi.org/10.3390/molecules16118992
_version_ 1783375469720109056
author Koutentis, Panayiotis A.
Koyioni, Maria
Michaelidou, Sophia S.
author_facet Koutentis, Panayiotis A.
Koyioni, Maria
Michaelidou, Sophia S.
author_sort Koutentis, Panayiotis A.
collection PubMed
description The reactions of 2-, 3- and 4-aminopyridines with 4,5-dichloro-1,2,3-dithiazol-ium chloride (Appel salt) 4 to give N-(4-chloro-5H-1,2,3-dithiazol-5-ylidene)pyridin-X-amines 1a (X = 2), 1g (X = 3) and 1k (X = 4) were optimized with respect to base, temperature and reaction time. Based on these conditions a total of thirteen [(dithiazol-ylidene)amino]azines 1a-m were prepared and fully characterized.
format Online
Article
Text
id pubmed-6264322
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-62643222018-12-10 Synthesis of [(4-Chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines Koutentis, Panayiotis A. Koyioni, Maria Michaelidou, Sophia S. Molecules Article The reactions of 2-, 3- and 4-aminopyridines with 4,5-dichloro-1,2,3-dithiazol-ium chloride (Appel salt) 4 to give N-(4-chloro-5H-1,2,3-dithiazol-5-ylidene)pyridin-X-amines 1a (X = 2), 1g (X = 3) and 1k (X = 4) were optimized with respect to base, temperature and reaction time. Based on these conditions a total of thirteen [(dithiazol-ylidene)amino]azines 1a-m were prepared and fully characterized. MDPI 2011-10-25 /pmc/articles/PMC6264322/ /pubmed/22442824 http://dx.doi.org/10.3390/molecules16118992 Text en © 2011 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Koutentis, Panayiotis A.
Koyioni, Maria
Michaelidou, Sophia S.
Synthesis of [(4-Chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines
title Synthesis of [(4-Chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines
title_full Synthesis of [(4-Chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines
title_fullStr Synthesis of [(4-Chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines
title_full_unstemmed Synthesis of [(4-Chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines
title_short Synthesis of [(4-Chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines
title_sort synthesis of [(4-chloro-5h-1,2,3-dithiazol-5-ylidene)amino]azines
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264322/
https://www.ncbi.nlm.nih.gov/pubmed/22442824
http://dx.doi.org/10.3390/molecules16118992
work_keys_str_mv AT koutentispanayiotisa synthesisof4chloro5h123dithiazol5ylideneaminoazines
AT koyionimaria synthesisof4chloro5h123dithiazol5ylideneaminoazines
AT michaelidousophias synthesisof4chloro5h123dithiazol5ylideneaminoazines

Ejemplares similares