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Two-Carbon Homologation of Aldehydes and Ketones to α,β-Unsaturated Aldehydes

Phosphonate reagents were developed for the two-carbon homologation of aldehydes or ketones to unbranched- or methyl-branched α,β-unsaturated aldehydes. The phosphonate reagents, diethyl methylformyl-2-phosphonate dimethylhydrazone and diethyl ethylformyl-2-phosphonate dimethylhydrazone, contained a...

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Detalles Bibliográficos
Autores principales: Petroski, Richard J., Vermillion, Karl, Cossé, Allard A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264399/
https://www.ncbi.nlm.nih.gov/pubmed/21694671
http://dx.doi.org/10.3390/molecules16065062

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