The 2-(Triphenylsilyl)ethoxycarbonyl-(“Tpseoc”-) Group: A New Silicon-Based, Fluoride Cleavable Oxycarbonyl Protecting Group Highly Orthogonal to the Boc-, Fmoc- and Cbz-Groups

Starting from 2-(triphenylsilyl)ethanol a new oxycarbonyl protecting group cleavable by fluoride ion induced Peterson-elimination has been developed. Known 2-(triphenylsilyl)ethanol has been prepared from commercially available triphenylvinyl-silane by a hydroboration-oxidation sequence using the st...

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Detalles Bibliográficos
Autores principales: Golkowski, Martin, Ziegler, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264494/
https://www.ncbi.nlm.nih.gov/pubmed/21654577
http://dx.doi.org/10.3390/molecules16064695

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264494/
https://www.ncbi.nlm.nih.gov/pubmed/21654577
http://dx.doi.org/10.3390/molecules16064695

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