Li(+) Selective Podand-Type Fluoroionophore Based on a Diphenyl Sulfoxide Derivative Bearing Two Pyrene Groups

New podand-type fluoroionophores having two pyrene moieties: 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfide (3), 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfoxide (4), and 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfone (5), have been synthesized by connecting two 1-pyrenecarbonylmethyl groups with the two...

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Autores principales: Nishimura, Yukihiro, Takemura, Tetsuo, Arai, Sadao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264584/
https://www.ncbi.nlm.nih.gov/pubmed/21832974
http://dx.doi.org/10.3390/molecules16086844
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author Nishimura, Yukihiro
Takemura, Tetsuo
Arai, Sadao
author_facet Nishimura, Yukihiro
Takemura, Tetsuo
Arai, Sadao
author_sort Nishimura, Yukihiro
collection PubMed
description New podand-type fluoroionophores having two pyrene moieties: 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfide (3), 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfoxide (4), and 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfone (5), have been synthesized by connecting two 1-pyrenecarbonylmethyl groups with the two hydroxy groups of 2,2´-dihydroxydiphenyl sulfide, sulfoxide, and sulfone, respectively. Their complexation behavior toward alkali metal ions was examined by fluorescence spectroscopy. Among these fluoroionophores, compound 4, having a sulfinyl group, showed high selectivity toward Li(+).
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spelling pubmed-62645842018-12-10 Li(+) Selective Podand-Type Fluoroionophore Based on a Diphenyl Sulfoxide Derivative Bearing Two Pyrene Groups Nishimura, Yukihiro Takemura, Tetsuo Arai, Sadao Molecules Article New podand-type fluoroionophores having two pyrene moieties: 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfide (3), 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfoxide (4), and 2,2´-bis(1-pyrenylacetyloxy)diphenyl sulfone (5), have been synthesized by connecting two 1-pyrenecarbonylmethyl groups with the two hydroxy groups of 2,2´-dihydroxydiphenyl sulfide, sulfoxide, and sulfone, respectively. Their complexation behavior toward alkali metal ions was examined by fluorescence spectroscopy. Among these fluoroionophores, compound 4, having a sulfinyl group, showed high selectivity toward Li(+). MDPI 2011-08-10 /pmc/articles/PMC6264584/ /pubmed/21832974 http://dx.doi.org/10.3390/molecules16086844 Text en © 2011 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Nishimura, Yukihiro
Takemura, Tetsuo
Arai, Sadao
Li(+) Selective Podand-Type Fluoroionophore Based on a Diphenyl Sulfoxide Derivative Bearing Two Pyrene Groups
title Li(+) Selective Podand-Type Fluoroionophore Based on a Diphenyl Sulfoxide Derivative Bearing Two Pyrene Groups
title_full Li(+) Selective Podand-Type Fluoroionophore Based on a Diphenyl Sulfoxide Derivative Bearing Two Pyrene Groups
title_fullStr Li(+) Selective Podand-Type Fluoroionophore Based on a Diphenyl Sulfoxide Derivative Bearing Two Pyrene Groups
title_full_unstemmed Li(+) Selective Podand-Type Fluoroionophore Based on a Diphenyl Sulfoxide Derivative Bearing Two Pyrene Groups
title_short Li(+) Selective Podand-Type Fluoroionophore Based on a Diphenyl Sulfoxide Derivative Bearing Two Pyrene Groups
title_sort li(+) selective podand-type fluoroionophore based on a diphenyl sulfoxide derivative bearing two pyrene groups
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264584/
https://www.ncbi.nlm.nih.gov/pubmed/21832974
http://dx.doi.org/10.3390/molecules16086844
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AT araisadao liselectivepodandtypefluoroionophorebasedonadiphenylsulfoxidederivativebearingtwopyrenegroups

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