Cargando…

Opportunities Offered by Chiral η(6)-Arene/N-Arylsulfonyl-diamine-Ru(II) Catalysts in the Asymmetric Transfer Hydrogenation of Ketones and Imines

Methods for the asymmetric transfer hydrogenation (ATH) of ketones and imines are still being intensively studied and developed. Of foremost interest is the use of Noyori’s [RuCl(η(6)-arene)(N-TsDPEN)] complexes in the presence of a hydrogen donor (i-PrOH, formic acid). These complexes have found nu...

Descripción completa

Detalles Bibliográficos
Autores principales:	Václavík, Jiří, Kačer, Petr, Kuzma, Marek, Červený, Libor
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2011
Materias:	Review
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264677/ https://www.ncbi.nlm.nih.gov/pubmed/21712760 http://dx.doi.org/10.3390/molecules16075460

Ejemplares similares

Asymmetric transfer hydrogenation of imines and ketones using chiral Ru(II)Cl(η(6)-p-cymene)[(S,S)-N-TsDPEN] catalyst: a computational study
por: Kačer, Petr, et al.
Publicado: (2012)

Computational evaluation of the η6-arene during the ATH of imines on Noyori’s RuII catalyst
por: Kacer, Petr, et al.
Publicado: (2014)

Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines
por: Václavík, Jiří, et al.
Publicado: (2014)

Practical Aspects and Mechanism of Asymmetric Hydrogenation with Chiral Half-Sandwich Complexes
por: Václavík, Jiří, et al.
Publicado: (2013)

Tricarbonyl(η6-Arene)Chromium(0) Complexes as Chiral Auxiliaries: Asymmetric Synthesis of β-Lactones
por: Buttero, Paola Del, et al.
Publicado: (2001)

Catalytic Asymmetric C–H Arylation of (η(6)-Arene)Chromium Complexes: Facile Access to Planar-Chiral Phosphines
por: Batuecas, María, et al.
Publicado: (2019)

Imine- and Amine-Type Macrocycles Derived from Chiral Diamines and Aromatic Dialdehydes
por: Lisowski, Jerzy
Publicado: (2022)

Unexpected chiral vicinal tetrasubstituted diamines via borylcopper-mediated homocoupling of isatin imines
por: Manenti, Marco, et al.
Publicado: (2022)

Access to Chiral Diamine Derivatives through Stereoselective Cu-Catalyzed Reductive Coupling of Imines and Allenamides
por: Agrawal, Toolika, et al.
Publicado: (2021)

Asymmetric hydrosilylation of ketones catalyzed by complexes formed from trans-diaminocyclohexane-based diamines and diethylzinc
por: Gajewy, Jadwiga, et al.
Publicado: (2012)

Enantioselective synthesis of α-amino ketones through palladium-catalyzed asymmetric arylation of α-keto imines
por: Wen, Wei, et al.
Publicado: (2022)

Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones
por: Narasimhan, S., et al.
Publicado: (2001)

Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium
por: Pégot, Bruce, et al.
Publicado: (2006)

Nickel-Catalyzed Asymmetric Hydrogenation of Cyclic Sulfamidate Imines: Efficient Synthesis of Chiral Cyclic Sulfamidates
por: Liu, Yuanhua, et al.
Publicado: (2019)

Asymmetric Aldol Reactions of α,β-Unsaturated Ketoester Substrates Catalyzed by Chiral Diamines
por: Kan, Sha-Sha, et al.
Publicado: (2011)

An (R)‐Imine Reductase Biocatalyst for the Asymmetric Reduction of Cyclic Imines
por: Hussain, Shahed, et al.
Publicado: (2015)

Design of Ru(II)-NHC-Diamine Precatalysts Directed by Ligand Cooperation: Applications and Mechanistic Investigations for Asymmetric Hydrogenation
por: Li, Wei, et al.
Publicado: (2020)

Application of molecular modelling in heterogeneous catalysis research
por: Kacer, P, et al.
Publicado: (2008)

Asymmetric Conjugate Addition of Ketones to Maleimides Organocatalyzed by a Chiral Primary Amine-Salicylamide
por: Torregrosa-Chinillach, Alejandro, et al.
Publicado: (2022)

Zn-Catalyzed Regioselective and Chemoselective Reduction of Aldehydes, Ketones and Imines
por: Zhang, Miaomiao, et al.
Publicado: (2022)

Catalytic Asymmetric Umpolung Reactions of Imines
por: Wu, Yongwei, et al.
Publicado: (2015)

Asymmetric Carbamoyl Anion Additions to Chiral N-Phosphonyl Imines via the GAP Chemistry Process and Stereoselectivity Enrichments
por: Seifert, Cole W., et al.
Publicado: (2014)

Asymmetric addition of α-branched cyclic ketones to allenamides catalyzed by a chiral phosphoric acid
por: Yang, Xiaoyu, et al.
Publicado: (2016)

Asymmetric Synthesis of Tetrahydroisoquinoline Derivatives through 1,3-Dipolar Cycloaddition of C,N-Cyclic Azomethine Imines with Allyl Alkyl Ketones
por: Feng, Guipeng, et al.
Publicado: (2021)

Synthesis and Anticancer Activity of [RuCl(2)(η(6)-arene)(aroylthiourea)] Complexes—High Activity against the Human Neuroblastoma (IMR-32) Cancer Cell Line
por: Swaminathan, Srividya, et al.
Publicado: (2019)

Intermolecular Chirality Modulation of Binaphthalene-Bridged Bisporphyrins With Chiral Diamines
por: Lu, Wenxin, et al.
Publicado: (2021)

Aromatic C-H addition of ketones to imines enabled by manganese catalysis
por: Zhou, Bingwei, et al.
Publicado: (2017)

New phosphine-diamine and phosphine-amino-alcohol tridentate ligands for ruthenium catalysed enantioselective hydrogenation of ketones and a concise lactone synthesis enabled by asymmetric reduction of cyano-ketones
por: Fuentes, José A, et al.
Publicado: (2012)

Asymmetric Reactions of N-Phosphonyl/Phosphoryl Imines
por: Ray, Devalina, et al.
Publicado: (2023)

Photorelease of Pyridyl Esters in Organometallic Ru(II) Arene Complexes
por: Habtemariam, Abraha, et al.
Publicado: (2015)

N (α)-arylsulfonyl histamines as selective β-glucosidase inhibitors
por: Salazar, M. O., et al.
Publicado: (2018)

Ru‐NHC‐Catalyzed Asymmetric Hydrogenation of 2‐Quinolones to Chiral 3,4‐Dihydro‐2‐Quinolones
por: Hu, Tianjiao, et al.
Publicado: (2021)

Ru-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes via P-Chiral Monophosphorous Ligands
por: Miao, Rui, et al.
Publicado: (2022)

Ru/g-C(3)N(4) as an efficient catalyst for selective hydrogenation of aromatic diamines to alicyclic diamines
por: Cao, Junya, et al.
Publicado: (2020)

trans-Diastereoselective Ru(II)-Catalyzed Asymmetric Transfer Hydrogenation of α-Acetamido Benzocyclic Ketones via Dynamic Kinetic Resolution
por: Cotman, Andrej Emanuel, et al.
Publicado: (2019)

Chiral Vicinal Diamines Derived from Mefloquine
por: Kucharski, Dawid J., et al.
Publicado: (2021)

A Mechanistic Study of Asymmetric Transfer Hydrogenation of Imines on a Chiral Phosphoric Acid Derived Indium Metal-Organic Framework
por: Li, Xu, et al.
Publicado: (2022)

Primary-tertiary diamine-catalyzed Michael addition of ketones to isatylidenemalononitrile derivatives
por: Kumar, Akshay, et al.
Publicado: (2014)

Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine
por: Wu, Kun, et al.
Publicado: (2015)

Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange
por: Soni, Rina, et al.
Publicado: (2013)

Cannot write session to /tmp/vufind_sessions/sess_juou9kk9uiu6k4ab8cclqgdk3u