Synthetic Organic Electrochemistry in Ionic Liquids: The Viscosity Question

Ionic liquids are obvious candidates for use in electrochemical applications due to their ionic character. Nevertheless, relatively little has been done to explore their application in electrosynthesis. We have studied the Shono oxidation of arylamines and carbamates using ionic liquids as recyclabl...

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Detalles Bibliográficos
Autores principales: Bornemann, Steven, Handy, Scott T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2011
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264684/
https://www.ncbi.nlm.nih.gov/pubmed/21769062
http://dx.doi.org/10.3390/molecules16075963
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author Bornemann, Steven
Handy, Scott T.
author_facet Bornemann, Steven
Handy, Scott T.
author_sort Bornemann, Steven
collection PubMed
description Ionic liquids are obvious candidates for use in electrochemical applications due to their ionic character. Nevertheless, relatively little has been done to explore their application in electrosynthesis. We have studied the Shono oxidation of arylamines and carbamates using ionic liquids as recyclable solvents and have noted that the viscosity of the medium is a major problem, although with the addition of sufficient co-solvent, good results and excellent recovery and recycling of the ionic liquid can be achieved.
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spelling pubmed-62646842018-12-10 Synthetic Organic Electrochemistry in Ionic Liquids: The Viscosity Question Bornemann, Steven Handy, Scott T. Molecules Article Ionic liquids are obvious candidates for use in electrochemical applications due to their ionic character. Nevertheless, relatively little has been done to explore their application in electrosynthesis. We have studied the Shono oxidation of arylamines and carbamates using ionic liquids as recyclable solvents and have noted that the viscosity of the medium is a major problem, although with the addition of sufficient co-solvent, good results and excellent recovery and recycling of the ionic liquid can be achieved. MDPI 2011-07-18 /pmc/articles/PMC6264684/ /pubmed/21769062 http://dx.doi.org/10.3390/molecules16075963 Text en © 2011 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Bornemann, Steven
Handy, Scott T.
Synthetic Organic Electrochemistry in Ionic Liquids: The Viscosity Question
title Synthetic Organic Electrochemistry in Ionic Liquids: The Viscosity Question
title_full Synthetic Organic Electrochemistry in Ionic Liquids: The Viscosity Question
title_fullStr Synthetic Organic Electrochemistry in Ionic Liquids: The Viscosity Question
title_full_unstemmed Synthetic Organic Electrochemistry in Ionic Liquids: The Viscosity Question
title_short Synthetic Organic Electrochemistry in Ionic Liquids: The Viscosity Question
title_sort synthetic organic electrochemistry in ionic liquids: the viscosity question
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264684/
https://www.ncbi.nlm.nih.gov/pubmed/21769062
http://dx.doi.org/10.3390/molecules16075963
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AT handyscottt syntheticorganicelectrochemistryinionicliquidstheviscosityquestion

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