High Performance Acetylene Sensor with Heterostructure Based on WO(3) Nanolamellae/Reduced Graphene Oxide (rGO) Nanosheets Operating at Low Temperature

The development of functionalized metal oxide/reduced graphene oxide (rGO) hybrid nanocomposites concerning power equipment failure diagnosis is one of the most recent topics. In this work, WO(3) nanolamellae/reduced graphene oxide (rGO) nanocomposites with different contents of GO (0.5 wt %, 1 wt %, 2 wt %, 4 wt %) were synthesized via controlled hydrothermal method. X-ray diffraction (XRD), transmission electron microscopy (TEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), thermogravimetric analyses-derivative thermogravimetric analysis-differential scanning calorimetry (TG-DTG-DSC), BET, and photoluminescence (PL) spectroscopy were utilized to investigate morphological characterizations of prepared gas sensing materials and indicated that high quality WO(3) nanolamellae were widely distributed among graphene sheets. Experimental ceramic planar gas sensors composing of interdigitated alumina substrates, Au electrodes, and RuO(2) heating layer were coated with WO(3) nanolamellae/reduced graphene oxide (rGO) films by spin-coating technique and then tested for gas sensing towards multi-concentrations of acetylene (C(2)H(2)) gases in a carrier gas with operating temperature ranging from 50 °C to 400 °C. Among four contents of prepared samples, sensing materials with 1 wt % GO nanocomposite exhibited the best C(2)H(2) sensing performance with lower optimal working temperature (150 °C), higher sensor response (15.0 toward 50 ppm), faster response-recovery time (52 s and 27 s), lower detection limitation (1.3 ppm), long-term stability, and excellent repeatability. The gas sensing mechanism for enhanced sensing performance of nanocomposite is possibly attributed to the formation of p-n heterojunction and the active interaction between WO(3) nanolamellae and rGO sheets. Besides, the introduction of rGO nanosheets leads to the impurity of synthesized materials, which creates more defects and promotes larger specific area for gas adsorption, outstanding conductivity, and faster carrier transport. The superior gas sensing properties of WO(3)/rGO based gas sensor may contribute to the development of a high-performance ppm-level gas sensor for the online monitoring of dissolved C(2)H(2) gas in large-scale transformer oil.