Photocatalytic Degradation of Methyl Orange over Metalloporphyrins Supported on TiO(2) Degussa P25

The photocatalytic activity of meso-tetraphenylporphyrins with different metal centers (Fe, Co, Mn and Cu) adsorbed on TiO(2) (Degussa P25) surface has been investigated by carrying out the photodegradation of methyl orange (MO) under visible and ultraviolet light irradiation. The photocatalysts wer...

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Autores principales: Zhou, Xian-Tai, Ji, Hong-Bing, Huang, Xing-Jiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268023/
https://www.ncbi.nlm.nih.gov/pubmed/22277995
http://dx.doi.org/10.3390/molecules17021149
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author Zhou, Xian-Tai
Ji, Hong-Bing
Huang, Xing-Jiao
author_facet Zhou, Xian-Tai
Ji, Hong-Bing
Huang, Xing-Jiao
author_sort Zhou, Xian-Tai
collection PubMed
description The photocatalytic activity of meso-tetraphenylporphyrins with different metal centers (Fe, Co, Mn and Cu) adsorbed on TiO(2) (Degussa P25) surface has been investigated by carrying out the photodegradation of methyl orange (MO) under visible and ultraviolet light irradiation. The photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflectance UV (DRS-UV-vis) and infrared spectra. Copper porphyrin-sensitized TiO(2) photocatalyst (CuP-TiO(2)) showed excellent activity for the photodegradation of MO whether under visible or ultraviolet light irradiation. Natural Bond Orbital (NBO) charges analysis showed that methyl orange ion is adsorbed easier by CuP-TiO(2) catalyst due to the increase of induced interactions.
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spelling pubmed-62680232018-12-10 Photocatalytic Degradation of Methyl Orange over Metalloporphyrins Supported on TiO(2) Degussa P25 Zhou, Xian-Tai Ji, Hong-Bing Huang, Xing-Jiao Molecules Article The photocatalytic activity of meso-tetraphenylporphyrins with different metal centers (Fe, Co, Mn and Cu) adsorbed on TiO(2) (Degussa P25) surface has been investigated by carrying out the photodegradation of methyl orange (MO) under visible and ultraviolet light irradiation. The photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflectance UV (DRS-UV-vis) and infrared spectra. Copper porphyrin-sensitized TiO(2) photocatalyst (CuP-TiO(2)) showed excellent activity for the photodegradation of MO whether under visible or ultraviolet light irradiation. Natural Bond Orbital (NBO) charges analysis showed that methyl orange ion is adsorbed easier by CuP-TiO(2) catalyst due to the increase of induced interactions. MDPI 2012-01-25 /pmc/articles/PMC6268023/ /pubmed/22277995 http://dx.doi.org/10.3390/molecules17021149 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Zhou, Xian-Tai
Ji, Hong-Bing
Huang, Xing-Jiao
Photocatalytic Degradation of Methyl Orange over Metalloporphyrins Supported on TiO(2) Degussa P25
title Photocatalytic Degradation of Methyl Orange over Metalloporphyrins Supported on TiO(2) Degussa P25
title_full Photocatalytic Degradation of Methyl Orange over Metalloporphyrins Supported on TiO(2) Degussa P25
title_fullStr Photocatalytic Degradation of Methyl Orange over Metalloporphyrins Supported on TiO(2) Degussa P25
title_full_unstemmed Photocatalytic Degradation of Methyl Orange over Metalloporphyrins Supported on TiO(2) Degussa P25
title_short Photocatalytic Degradation of Methyl Orange over Metalloporphyrins Supported on TiO(2) Degussa P25
title_sort photocatalytic degradation of methyl orange over metalloporphyrins supported on tio(2) degussa p25
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268023/
https://www.ncbi.nlm.nih.gov/pubmed/22277995
http://dx.doi.org/10.3390/molecules17021149
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AT jihongbing photocatalyticdegradationofmethylorangeovermetalloporphyrinssupportedontio2degussap25
AT huangxingjiao photocatalyticdegradationofmethylorangeovermetalloporphyrinssupportedontio2degussap25

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