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Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural

Homogenous bis-sulfonic acid ionic liquids (1 mol equiv.) in DMSO (10 mol equiv.) at 100 °C efficiently mediated the conversion of D-fructose into 5-hydroxymethyl-2-furfural in 75% isolated yield, which was roughly a 10% increment compared to the case of the mono-sulfonic acid ionic liquids.

Detalles Bibliográficos
Autores principales: Sim, Sang Eun, Kwon, Sunjeong, Koo, Sangho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268089/
https://www.ncbi.nlm.nih.gov/pubmed/23114616
http://dx.doi.org/10.3390/molecules171112804
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author Sim, Sang Eun
Kwon, Sunjeong
Koo, Sangho
author_facet Sim, Sang Eun
Kwon, Sunjeong
Koo, Sangho
author_sort Sim, Sang Eun
collection PubMed
description Homogenous bis-sulfonic acid ionic liquids (1 mol equiv.) in DMSO (10 mol equiv.) at 100 °C efficiently mediated the conversion of D-fructose into 5-hydroxymethyl-2-furfural in 75% isolated yield, which was roughly a 10% increment compared to the case of the mono-sulfonic acid ionic liquids.
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spelling pubmed-62680892018-12-13 Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural Sim, Sang Eun Kwon, Sunjeong Koo, Sangho Molecules Communication Homogenous bis-sulfonic acid ionic liquids (1 mol equiv.) in DMSO (10 mol equiv.) at 100 °C efficiently mediated the conversion of D-fructose into 5-hydroxymethyl-2-furfural in 75% isolated yield, which was roughly a 10% increment compared to the case of the mono-sulfonic acid ionic liquids. MDPI 2012-10-31 /pmc/articles/PMC6268089/ /pubmed/23114616 http://dx.doi.org/10.3390/molecules171112804 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Communication
Sim, Sang Eun
Kwon, Sunjeong
Koo, Sangho
Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural
title Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural
title_full Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural
title_fullStr Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural
title_full_unstemmed Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural
title_short Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural
title_sort bis-sulfonic acid ionic liquids for the conversion of fructose to 5-hydroxymethyl-2-furfural
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268089/
https://www.ncbi.nlm.nih.gov/pubmed/23114616
http://dx.doi.org/10.3390/molecules171112804
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