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Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural
Homogenous bis-sulfonic acid ionic liquids (1 mol equiv.) in DMSO (10 mol equiv.) at 100 °C efficiently mediated the conversion of D-fructose into 5-hydroxymethyl-2-furfural in 75% isolated yield, which was roughly a 10% increment compared to the case of the mono-sulfonic acid ionic liquids.
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268089/ https://www.ncbi.nlm.nih.gov/pubmed/23114616 http://dx.doi.org/10.3390/molecules171112804 |
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author | Sim, Sang Eun Kwon, Sunjeong Koo, Sangho |
author_facet | Sim, Sang Eun Kwon, Sunjeong Koo, Sangho |
author_sort | Sim, Sang Eun |
collection | PubMed |
description | Homogenous bis-sulfonic acid ionic liquids (1 mol equiv.) in DMSO (10 mol equiv.) at 100 °C efficiently mediated the conversion of D-fructose into 5-hydroxymethyl-2-furfural in 75% isolated yield, which was roughly a 10% increment compared to the case of the mono-sulfonic acid ionic liquids. |
format | Online Article Text |
id | pubmed-6268089 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-62680892018-12-13 Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural Sim, Sang Eun Kwon, Sunjeong Koo, Sangho Molecules Communication Homogenous bis-sulfonic acid ionic liquids (1 mol equiv.) in DMSO (10 mol equiv.) at 100 °C efficiently mediated the conversion of D-fructose into 5-hydroxymethyl-2-furfural in 75% isolated yield, which was roughly a 10% increment compared to the case of the mono-sulfonic acid ionic liquids. MDPI 2012-10-31 /pmc/articles/PMC6268089/ /pubmed/23114616 http://dx.doi.org/10.3390/molecules171112804 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). |
spellingShingle | Communication Sim, Sang Eun Kwon, Sunjeong Koo, Sangho Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural |
title | Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural |
title_full | Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural |
title_fullStr | Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural |
title_full_unstemmed | Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural |
title_short | Bis-sulfonic Acid Ionic Liquids for the Conversion of Fructose to 5-Hydroxymethyl-2-furfural |
title_sort | bis-sulfonic acid ionic liquids for the conversion of fructose to 5-hydroxymethyl-2-furfural |
topic | Communication |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268089/ https://www.ncbi.nlm.nih.gov/pubmed/23114616 http://dx.doi.org/10.3390/molecules171112804 |
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