The Role of Water in Lanthanide-Catalyzed Carbon–Carbon Bond Formation

Luminescence-decay measurements in combination with high-performance liquid chromatography analyses were used to study the relationship between rates of catalysis and water-coordination numbers of europium-based precatalysts in the aqueous Mukaiyama aldol reaction. A correlation between reactivity a...

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Autores principales: Averill, Derek J., Dissanayake, Prabani, Allen, Matthew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268264/
https://www.ncbi.nlm.nih.gov/pubmed/22349897
http://dx.doi.org/10.3390/molecules17022073
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author Averill, Derek J.
Dissanayake, Prabani
Allen, Matthew J.
author_facet Averill, Derek J.
Dissanayake, Prabani
Allen, Matthew J.
author_sort Averill, Derek J.
collection PubMed
description Luminescence-decay measurements in combination with high-performance liquid chromatography analyses were used to study the relationship between rates of catalysis and water-coordination numbers of europium-based precatalysts in the aqueous Mukaiyama aldol reaction. A correlation between reactivity and water-coordination number was observed and is reported here.
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spelling pubmed-62682642018-12-10 The Role of Water in Lanthanide-Catalyzed Carbon–Carbon Bond Formation Averill, Derek J. Dissanayake, Prabani Allen, Matthew J. Molecules Article Luminescence-decay measurements in combination with high-performance liquid chromatography analyses were used to study the relationship between rates of catalysis and water-coordination numbers of europium-based precatalysts in the aqueous Mukaiyama aldol reaction. A correlation between reactivity and water-coordination number was observed and is reported here. MDPI 2012-02-20 /pmc/articles/PMC6268264/ /pubmed/22349897 http://dx.doi.org/10.3390/molecules17022073 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Averill, Derek J.
Dissanayake, Prabani
Allen, Matthew J.
The Role of Water in Lanthanide-Catalyzed Carbon–Carbon Bond Formation
title The Role of Water in Lanthanide-Catalyzed Carbon–Carbon Bond Formation
title_full The Role of Water in Lanthanide-Catalyzed Carbon–Carbon Bond Formation
title_fullStr The Role of Water in Lanthanide-Catalyzed Carbon–Carbon Bond Formation
title_full_unstemmed The Role of Water in Lanthanide-Catalyzed Carbon–Carbon Bond Formation
title_short The Role of Water in Lanthanide-Catalyzed Carbon–Carbon Bond Formation
title_sort role of water in lanthanide-catalyzed carbon–carbon bond formation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268264/
https://www.ncbi.nlm.nih.gov/pubmed/22349897
http://dx.doi.org/10.3390/molecules17022073
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