A Convenient Synthesis of Triflate Anion Ionic Liquids and Their Properties

A solvent- and halogen-free synthesis of high purity triflate ionic liquids via direct alkylation of organic bases (amines, phosphines or heterocyclic compounds) with methyl and ethyl trifluoromethanesulfonate (methyl and ethyl triflate) has been developed. Cheap and non-toxic dimethyl and diethyl c...

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Detalles Bibliográficos
Autores principales: Ignat’ev, Nikolai V., Barthen, Peter, Kucheryna, Andryi, Willner, Helge, Sartori, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268271/
https://www.ncbi.nlm.nih.gov/pubmed/22565482
http://dx.doi.org/10.3390/molecules17055319
Descripción
Sumario:A solvent- and halogen-free synthesis of high purity triflate ionic liquids via direct alkylation of organic bases (amines, phosphines or heterocyclic compounds) with methyl and ethyl trifluoromethanesulfonate (methyl and ethyl triflate) has been developed. Cheap and non-toxic dimethyl and diethyl carbonate serve as source for the methyl and ethyl groups in the preparation of methyl and ethyl triflate by this invented process. The properties of ionic liquids containing the triflate anion are determined and discussed.

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