Recent Developments in the Reformatsky-Claisen Rearrangement

The rearrangement of allyl α-bromoacetates with Zn dust is known as the Reformatsky-Claisen rearrangement. Whereas the Ireland-Claisen rearrangement has been widely used in the synthesis of a diverse range of natural products, the Zn-mediated Reformatsky-Claisen rearrangement has not been utilized s...

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Detalles Bibliográficos
Autores principales: Ishihara, Jun, Hatakeyama, Susumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268371/
https://www.ncbi.nlm.nih.gov/pubmed/23201643
http://dx.doi.org/10.3390/molecules171214249
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author Ishihara, Jun
Hatakeyama, Susumi
author_facet Ishihara, Jun
Hatakeyama, Susumi
author_sort Ishihara, Jun
collection PubMed
description The rearrangement of allyl α-bromoacetates with Zn dust is known as the Reformatsky-Claisen rearrangement. Whereas the Ireland-Claisen rearrangement has been widely used in the synthesis of a diverse range of natural products, the Zn-mediated Reformatsky-Claisen rearrangement has not been utilized so often. In this article, we will provide an overview of recent advances in the Reformatsky-Claisen rearrangement field, including the In-mediated Reformatsky-Claisen rearrangement we have recently developed.
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spelling pubmed-62683712018-12-14 Recent Developments in the Reformatsky-Claisen Rearrangement Ishihara, Jun Hatakeyama, Susumi Molecules Review The rearrangement of allyl α-bromoacetates with Zn dust is known as the Reformatsky-Claisen rearrangement. Whereas the Ireland-Claisen rearrangement has been widely used in the synthesis of a diverse range of natural products, the Zn-mediated Reformatsky-Claisen rearrangement has not been utilized so often. In this article, we will provide an overview of recent advances in the Reformatsky-Claisen rearrangement field, including the In-mediated Reformatsky-Claisen rearrangement we have recently developed. MDPI 2012-11-30 /pmc/articles/PMC6268371/ /pubmed/23201643 http://dx.doi.org/10.3390/molecules171214249 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Review
Ishihara, Jun
Hatakeyama, Susumi
Recent Developments in the Reformatsky-Claisen Rearrangement
title Recent Developments in the Reformatsky-Claisen Rearrangement
title_full Recent Developments in the Reformatsky-Claisen Rearrangement
title_fullStr Recent Developments in the Reformatsky-Claisen Rearrangement
title_full_unstemmed Recent Developments in the Reformatsky-Claisen Rearrangement
title_short Recent Developments in the Reformatsky-Claisen Rearrangement
title_sort recent developments in the reformatsky-claisen rearrangement
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268371/
https://www.ncbi.nlm.nih.gov/pubmed/23201643
http://dx.doi.org/10.3390/molecules171214249
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