Electrospray Ionization Mass Spectrometric Analysis of Highly Reactive Glycosyl Halides

Highly reactive glycosyl chlorides and bromides have been analysed by a routine mass spectrometric method using electrospray ionization and lithium salt adduct-forming agents in anhydrous acetonitrile solution, providing salient lithiated molecular ions [M+Li](+), [2M+Li](+)etc. The role of other ad...

Descripción completa

Detalles Bibliográficos
Autores principales: Bokros, Attila, Bánfi, Annamária, Kupihár, Zoltán, Kele, Zoltán, Illyés, Tünde Zita, Szolomájer, János, Kovács, Lajos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268470/
https://www.ncbi.nlm.nih.gov/pubmed/22781445
http://dx.doi.org/10.3390/molecules17078351
_version_ 1783376294457638912
author Bokros, Attila
Bánfi, Annamária
Kupihár, Zoltán
Kele, Zoltán
Illyés, Tünde Zita
Szolomájer, János
Kovács, Lajos
author_facet Bokros, Attila
Bánfi, Annamária
Kupihár, Zoltán
Kele, Zoltán
Illyés, Tünde Zita
Szolomájer, János
Kovács, Lajos
author_sort Bokros, Attila
collection PubMed
description Highly reactive glycosyl chlorides and bromides have been analysed by a routine mass spectrometric method using electrospray ionization and lithium salt adduct-forming agents in anhydrous acetonitrile solution, providing salient lithiated molecular ions [M+Li](+), [2M+Li](+)etc. The role of other adduct-forming salts has also been evaluated. The lithium salt method is useful for accurate mass determination of these highly sensitive compounds.
format Online
Article
Text
id pubmed-6268470
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-62684702018-12-12 Electrospray Ionization Mass Spectrometric Analysis of Highly Reactive Glycosyl Halides Bokros, Attila Bánfi, Annamária Kupihár, Zoltán Kele, Zoltán Illyés, Tünde Zita Szolomájer, János Kovács, Lajos Molecules Communication Highly reactive glycosyl chlorides and bromides have been analysed by a routine mass spectrometric method using electrospray ionization and lithium salt adduct-forming agents in anhydrous acetonitrile solution, providing salient lithiated molecular ions [M+Li](+), [2M+Li](+)etc. The role of other adduct-forming salts has also been evaluated. The lithium salt method is useful for accurate mass determination of these highly sensitive compounds. MDPI 2012-07-10 /pmc/articles/PMC6268470/ /pubmed/22781445 http://dx.doi.org/10.3390/molecules17078351 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Communication
Bokros, Attila
Bánfi, Annamária
Kupihár, Zoltán
Kele, Zoltán
Illyés, Tünde Zita
Szolomájer, János
Kovács, Lajos
Electrospray Ionization Mass Spectrometric Analysis of Highly Reactive Glycosyl Halides
title Electrospray Ionization Mass Spectrometric Analysis of Highly Reactive Glycosyl Halides
title_full Electrospray Ionization Mass Spectrometric Analysis of Highly Reactive Glycosyl Halides
title_fullStr Electrospray Ionization Mass Spectrometric Analysis of Highly Reactive Glycosyl Halides
title_full_unstemmed Electrospray Ionization Mass Spectrometric Analysis of Highly Reactive Glycosyl Halides
title_short Electrospray Ionization Mass Spectrometric Analysis of Highly Reactive Glycosyl Halides
title_sort electrospray ionization mass spectrometric analysis of highly reactive glycosyl halides
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268470/
https://www.ncbi.nlm.nih.gov/pubmed/22781445
http://dx.doi.org/10.3390/molecules17078351
work_keys_str_mv AT bokrosattila electrosprayionizationmassspectrometricanalysisofhighlyreactiveglycosylhalides
AT banfiannamaria electrosprayionizationmassspectrometricanalysisofhighlyreactiveglycosylhalides
AT kupiharzoltan electrosprayionizationmassspectrometricanalysisofhighlyreactiveglycosylhalides
AT kelezoltan electrosprayionizationmassspectrometricanalysisofhighlyreactiveglycosylhalides
AT illyestundezita electrosprayionizationmassspectrometricanalysisofhighlyreactiveglycosylhalides
AT szolomajerjanos electrosprayionizationmassspectrometricanalysisofhighlyreactiveglycosylhalides
AT kovacslajos electrosprayionizationmassspectrometricanalysisofhighlyreactiveglycosylhalides

Ejemplares similares