Azide-Alkyne Huisgen [3+2] Cycloaddition Using CuO Nanoparticles

Recent developments in the synthesis of SpellECuO nanoparticles (NPs) and their application to the [3+2] cycloaddition of azides with terminal alkynes are reviewed. With respect to the importance of click chemistry, CuO hollow NPs, CuO hollow NPs on acetylene black, water-soluble double-hydrophilic...

Descripción completa

Detalles Bibliográficos
Autores principales: Woo, Hyunje, Kang, Hyuntae, Kim, Aram, Jang, Seongwan, Park, Ji Chan, Park, Sungkyun, Kim, Byeong-Su, Song, Hyunjoon, Park, Kang Hyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268562/
https://www.ncbi.nlm.nih.gov/pubmed/23132140
http://dx.doi.org/10.3390/molecules171113235
_version_ 1783376314975125504
author Woo, Hyunje
Kang, Hyuntae
Kim, Aram
Jang, Seongwan
Park, Ji Chan
Park, Sungkyun
Kim, Byeong-Su
Song, Hyunjoon
Park, Kang Hyun
author_facet Woo, Hyunje
Kang, Hyuntae
Kim, Aram
Jang, Seongwan
Park, Ji Chan
Park, Sungkyun
Kim, Byeong-Su
Song, Hyunjoon
Park, Kang Hyun
author_sort Woo, Hyunje
collection PubMed
description Recent developments in the synthesis of SpellECuO nanoparticles (NPs) and their application to the [3+2] cycloaddition of azides with terminal alkynes are reviewed. With respect to the importance of click chemistry, CuO hollow NPs, CuO hollow NPs on acetylene black, water-soluble double-hydrophilic block copolymer (DHBC) nanoreactors and ZnO–CuO hybrid NPs were synthesized. Non-conventional energy sources such as microwaves and ultrasound were also applied to these click reactions, and good catalytic activity with high regioselectivity was observed. CuO hollow NPs on acetylene black can be recycled nine times without any loss of activity, and water-soluble DHBC nanoreactors have been developed for an environmentally friendly process.
format Online
Article
Text
id pubmed-6268562
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-62685622018-12-13 Azide-Alkyne Huisgen [3+2] Cycloaddition Using CuO Nanoparticles Woo, Hyunje Kang, Hyuntae Kim, Aram Jang, Seongwan Park, Ji Chan Park, Sungkyun Kim, Byeong-Su Song, Hyunjoon Park, Kang Hyun Molecules Review Recent developments in the synthesis of SpellECuO nanoparticles (NPs) and their application to the [3+2] cycloaddition of azides with terminal alkynes are reviewed. With respect to the importance of click chemistry, CuO hollow NPs, CuO hollow NPs on acetylene black, water-soluble double-hydrophilic block copolymer (DHBC) nanoreactors and ZnO–CuO hybrid NPs were synthesized. Non-conventional energy sources such as microwaves and ultrasound were also applied to these click reactions, and good catalytic activity with high regioselectivity was observed. CuO hollow NPs on acetylene black can be recycled nine times without any loss of activity, and water-soluble DHBC nanoreactors have been developed for an environmentally friendly process. MDPI 2012-11-06 /pmc/articles/PMC6268562/ /pubmed/23132140 http://dx.doi.org/10.3390/molecules171113235 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Review
Woo, Hyunje
Kang, Hyuntae
Kim, Aram
Jang, Seongwan
Park, Ji Chan
Park, Sungkyun
Kim, Byeong-Su
Song, Hyunjoon
Park, Kang Hyun
Azide-Alkyne Huisgen [3+2] Cycloaddition Using CuO Nanoparticles
title Azide-Alkyne Huisgen [3+2] Cycloaddition Using CuO Nanoparticles
title_full Azide-Alkyne Huisgen [3+2] Cycloaddition Using CuO Nanoparticles
title_fullStr Azide-Alkyne Huisgen [3+2] Cycloaddition Using CuO Nanoparticles
title_full_unstemmed Azide-Alkyne Huisgen [3+2] Cycloaddition Using CuO Nanoparticles
title_short Azide-Alkyne Huisgen [3+2] Cycloaddition Using CuO Nanoparticles
title_sort azide-alkyne huisgen [3+2] cycloaddition using cuo nanoparticles
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268562/
https://www.ncbi.nlm.nih.gov/pubmed/23132140
http://dx.doi.org/10.3390/molecules171113235
work_keys_str_mv AT woohyunje azidealkynehuisgen32cycloadditionusingcuonanoparticles
AT kanghyuntae azidealkynehuisgen32cycloadditionusingcuonanoparticles
AT kimaram azidealkynehuisgen32cycloadditionusingcuonanoparticles
AT jangseongwan azidealkynehuisgen32cycloadditionusingcuonanoparticles
AT parkjichan azidealkynehuisgen32cycloadditionusingcuonanoparticles
AT parksungkyun azidealkynehuisgen32cycloadditionusingcuonanoparticles
AT kimbyeongsu azidealkynehuisgen32cycloadditionusingcuonanoparticles
AT songhyunjoon azidealkynehuisgen32cycloadditionusingcuonanoparticles
AT parkkanghyun azidealkynehuisgen32cycloadditionusingcuonanoparticles

Ejemplares similares