Synthesis of Electronically Modified Ru-Based Neutral 16 VE Allenylidene Olefin Metathesis Precatalysts

Electronic modifications within Ru-based olefin metathesis precatalysts have provided a number of new complexes with significant differences in reactivity profiles. So far, this aspect has not been studied for neutral 16 VE allenylidenes. The first synthesis of electronically altered complexes of th...

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Detalles Bibliográficos
Autores principales: Lichtenheldt, Martin, Kress, Steffen, Blechert, Siegfried
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268640/
https://www.ncbi.nlm.nih.gov/pubmed/22628039
http://dx.doi.org/10.3390/molecules17055177
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author Lichtenheldt, Martin
Kress, Steffen
Blechert, Siegfried
author_facet Lichtenheldt, Martin
Kress, Steffen
Blechert, Siegfried
author_sort Lichtenheldt, Martin
collection PubMed
description Electronic modifications within Ru-based olefin metathesis precatalysts have provided a number of new complexes with significant differences in reactivity profiles. So far, this aspect has not been studied for neutral 16 VE allenylidenes. The first synthesis of electronically altered complexes of this type is reported. Following the classical dehydration approach (vide infra) modified propargyl alcohols were transformed to the targeted allenylidene systems in the presence of PCy(3). The catalytic performance was investigated in RCM reaction (ring closing metathesis) of benchmark substrates such as diallyltosylamide (6) and diethyl diallylmalonate (7).
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spelling pubmed-62686402018-12-20 Synthesis of Electronically Modified Ru-Based Neutral 16 VE Allenylidene Olefin Metathesis Precatalysts Lichtenheldt, Martin Kress, Steffen Blechert, Siegfried Molecules Communication Electronic modifications within Ru-based olefin metathesis precatalysts have provided a number of new complexes with significant differences in reactivity profiles. So far, this aspect has not been studied for neutral 16 VE allenylidenes. The first synthesis of electronically altered complexes of this type is reported. Following the classical dehydration approach (vide infra) modified propargyl alcohols were transformed to the targeted allenylidene systems in the presence of PCy(3). The catalytic performance was investigated in RCM reaction (ring closing metathesis) of benchmark substrates such as diallyltosylamide (6) and diethyl diallylmalonate (7). MDPI 2012-05-04 /pmc/articles/PMC6268640/ /pubmed/22628039 http://dx.doi.org/10.3390/molecules17055177 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Communication
Lichtenheldt, Martin
Kress, Steffen
Blechert, Siegfried
Synthesis of Electronically Modified Ru-Based Neutral 16 VE Allenylidene Olefin Metathesis Precatalysts
title Synthesis of Electronically Modified Ru-Based Neutral 16 VE Allenylidene Olefin Metathesis Precatalysts
title_full Synthesis of Electronically Modified Ru-Based Neutral 16 VE Allenylidene Olefin Metathesis Precatalysts
title_fullStr Synthesis of Electronically Modified Ru-Based Neutral 16 VE Allenylidene Olefin Metathesis Precatalysts
title_full_unstemmed Synthesis of Electronically Modified Ru-Based Neutral 16 VE Allenylidene Olefin Metathesis Precatalysts
title_short Synthesis of Electronically Modified Ru-Based Neutral 16 VE Allenylidene Olefin Metathesis Precatalysts
title_sort synthesis of electronically modified ru-based neutral 16 ve allenylidene olefin metathesis precatalysts
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268640/
https://www.ncbi.nlm.nih.gov/pubmed/22628039
http://dx.doi.org/10.3390/molecules17055177
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AT kresssteffen synthesisofelectronicallymodifiedrubasedneutral16veallenylideneolefinmetathesisprecatalysts
AT blechertsiegfried synthesisofelectronicallymodifiedrubasedneutral16veallenylideneolefinmetathesisprecatalysts

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