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Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems

The effect of curing agent (6610) content and temperature on the rheological behavior of the epoxy resin CYD-128 was studied by DSC analysis and viscosity experiments. The results show that the resin system meets the requirements of processing technology. A complete reaction occurs when the curing a...

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Detalles Bibliográficos
Autores principales: Zhao, Chenhui, Zhang, Guangcheng, Zhao, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268763/
https://www.ncbi.nlm.nih.gov/pubmed/22805509
http://dx.doi.org/10.3390/molecules17078587
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author Zhao, Chenhui
Zhang, Guangcheng
Zhao, Lei
author_facet Zhao, Chenhui
Zhang, Guangcheng
Zhao, Lei
author_sort Zhao, Chenhui
collection PubMed
description The effect of curing agent (6610) content and temperature on the rheological behavior of the epoxy resin CYD-128 was studied by DSC analysis and viscosity experiments. The results show that the resin system meets the requirements of processing technology. A complete reaction occurs when the curing agent content (40 parts per hundred resin, phr) is a little higher than the theoretical value (33.33 phr), while the degree of reaction of the resin system is reduced when the curing agent content is lower (25.00 phr) than theoretical value. However, excessive curing agent (50.00 phr) results in a lower reaction rate. Curing agent content has little influence on gel time when curing agent content exceeded 33.33 phr and the temperature was less than 70 °C. The isothermal viscosity-time curves shift towards the –x axis when the temperature rises from 50 °C to 80 °C. Meanwhile, higher temperature results in higher reaction rates.
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spelling pubmed-62687632018-12-12 Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems Zhao, Chenhui Zhang, Guangcheng Zhao, Lei Molecules Article The effect of curing agent (6610) content and temperature on the rheological behavior of the epoxy resin CYD-128 was studied by DSC analysis and viscosity experiments. The results show that the resin system meets the requirements of processing technology. A complete reaction occurs when the curing agent content (40 parts per hundred resin, phr) is a little higher than the theoretical value (33.33 phr), while the degree of reaction of the resin system is reduced when the curing agent content is lower (25.00 phr) than theoretical value. However, excessive curing agent (50.00 phr) results in a lower reaction rate. Curing agent content has little influence on gel time when curing agent content exceeded 33.33 phr and the temperature was less than 70 °C. The isothermal viscosity-time curves shift towards the –x axis when the temperature rises from 50 °C to 80 °C. Meanwhile, higher temperature results in higher reaction rates. MDPI 2012-07-17 /pmc/articles/PMC6268763/ /pubmed/22805509 http://dx.doi.org/10.3390/molecules17078587 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Zhao, Chenhui
Zhang, Guangcheng
Zhao, Lei
Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems
title Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems
title_full Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems
title_fullStr Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems
title_full_unstemmed Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems
title_short Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems
title_sort effect of curing agent and temperature on the rheological behavior of epoxy resin systems
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268763/
https://www.ncbi.nlm.nih.gov/pubmed/22805509
http://dx.doi.org/10.3390/molecules17078587
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