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Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems
The effect of curing agent (6610) content and temperature on the rheological behavior of the epoxy resin CYD-128 was studied by DSC analysis and viscosity experiments. The results show that the resin system meets the requirements of processing technology. A complete reaction occurs when the curing a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268763/ https://www.ncbi.nlm.nih.gov/pubmed/22805509 http://dx.doi.org/10.3390/molecules17078587 |
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author | Zhao, Chenhui Zhang, Guangcheng Zhao, Lei |
author_facet | Zhao, Chenhui Zhang, Guangcheng Zhao, Lei |
author_sort | Zhao, Chenhui |
collection | PubMed |
description | The effect of curing agent (6610) content and temperature on the rheological behavior of the epoxy resin CYD-128 was studied by DSC analysis and viscosity experiments. The results show that the resin system meets the requirements of processing technology. A complete reaction occurs when the curing agent content (40 parts per hundred resin, phr) is a little higher than the theoretical value (33.33 phr), while the degree of reaction of the resin system is reduced when the curing agent content is lower (25.00 phr) than theoretical value. However, excessive curing agent (50.00 phr) results in a lower reaction rate. Curing agent content has little influence on gel time when curing agent content exceeded 33.33 phr and the temperature was less than 70 °C. The isothermal viscosity-time curves shift towards the –x axis when the temperature rises from 50 °C to 80 °C. Meanwhile, higher temperature results in higher reaction rates. |
format | Online Article Text |
id | pubmed-6268763 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-62687632018-12-12 Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems Zhao, Chenhui Zhang, Guangcheng Zhao, Lei Molecules Article The effect of curing agent (6610) content and temperature on the rheological behavior of the epoxy resin CYD-128 was studied by DSC analysis and viscosity experiments. The results show that the resin system meets the requirements of processing technology. A complete reaction occurs when the curing agent content (40 parts per hundred resin, phr) is a little higher than the theoretical value (33.33 phr), while the degree of reaction of the resin system is reduced when the curing agent content is lower (25.00 phr) than theoretical value. However, excessive curing agent (50.00 phr) results in a lower reaction rate. Curing agent content has little influence on gel time when curing agent content exceeded 33.33 phr and the temperature was less than 70 °C. The isothermal viscosity-time curves shift towards the –x axis when the temperature rises from 50 °C to 80 °C. Meanwhile, higher temperature results in higher reaction rates. MDPI 2012-07-17 /pmc/articles/PMC6268763/ /pubmed/22805509 http://dx.doi.org/10.3390/molecules17078587 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). |
spellingShingle | Article Zhao, Chenhui Zhang, Guangcheng Zhao, Lei Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems |
title | Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems |
title_full | Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems |
title_fullStr | Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems |
title_full_unstemmed | Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems |
title_short | Effect of Curing Agent and Temperature on the Rheological Behavior of Epoxy Resin Systems |
title_sort | effect of curing agent and temperature on the rheological behavior of epoxy resin systems |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268763/ https://www.ncbi.nlm.nih.gov/pubmed/22805509 http://dx.doi.org/10.3390/molecules17078587 |
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