Recent Applications of the (TMS)(3)SiH Radical-Based Reagent

This review article focuses on the recent applications of tris(trimethylsilyl)silane as a radical-based reagent in organic chemistry. Numerous examples of the successful use of (TMS)(3)SiH in radical reductions, hydrosilylation and consecutive radical reactions are given. The use of (TMS)(3)SiH allo...

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Detalles Bibliográficos
Autores principales: Chatgilialoglu, Chryssostomos, Lalevée, Jacques
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268903/
https://www.ncbi.nlm.nih.gov/pubmed/22269866
http://dx.doi.org/10.3390/molecules17010527
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author Chatgilialoglu, Chryssostomos
Lalevée, Jacques
author_facet Chatgilialoglu, Chryssostomos
Lalevée, Jacques
author_sort Chatgilialoglu, Chryssostomos
collection PubMed
description This review article focuses on the recent applications of tris(trimethylsilyl)silane as a radical-based reagent in organic chemistry. Numerous examples of the successful use of (TMS)(3)SiH in radical reductions, hydrosilylation and consecutive radical reactions are given. The use of (TMS)(3)SiH allows reactions to be carried out under mild conditions with excellent yields of products and remarkable chemo-, regio-, and stereoselectivity. The strategic role of (TMS)(3)SiH in polymerization is underlined with emphasis on the photo-induced radical polymerization of olefins and photo-promoted cationic polymerization of epoxides.
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spelling pubmed-62689032018-12-11 Recent Applications of the (TMS)(3)SiH Radical-Based Reagent Chatgilialoglu, Chryssostomos Lalevée, Jacques Molecules Review This review article focuses on the recent applications of tris(trimethylsilyl)silane as a radical-based reagent in organic chemistry. Numerous examples of the successful use of (TMS)(3)SiH in radical reductions, hydrosilylation and consecutive radical reactions are given. The use of (TMS)(3)SiH allows reactions to be carried out under mild conditions with excellent yields of products and remarkable chemo-, regio-, and stereoselectivity. The strategic role of (TMS)(3)SiH in polymerization is underlined with emphasis on the photo-induced radical polymerization of olefins and photo-promoted cationic polymerization of epoxides. MDPI 2012-01-06 /pmc/articles/PMC6268903/ /pubmed/22269866 http://dx.doi.org/10.3390/molecules17010527 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Review
Chatgilialoglu, Chryssostomos
Lalevée, Jacques
Recent Applications of the (TMS)(3)SiH Radical-Based Reagent
title Recent Applications of the (TMS)(3)SiH Radical-Based Reagent
title_full Recent Applications of the (TMS)(3)SiH Radical-Based Reagent
title_fullStr Recent Applications of the (TMS)(3)SiH Radical-Based Reagent
title_full_unstemmed Recent Applications of the (TMS)(3)SiH Radical-Based Reagent
title_short Recent Applications of the (TMS)(3)SiH Radical-Based Reagent
title_sort recent applications of the (tms)(3)sih radical-based reagent
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6268903/
https://www.ncbi.nlm.nih.gov/pubmed/22269866
http://dx.doi.org/10.3390/molecules17010527
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