Synthesis of δ-Oxo-1,1-bis(triflyl)alkanes and Their Acidities

The reaction of 1,1-bis(triflyl)ethylene generated in situ with enolizable carbonyls yielded δ-oxo-1,1-bis(triflyl)alkane derivatives. Their acidities in both the gas and solution phases were determined.

Detalles Bibliográficos
Autores principales: Yanai, Hikaru, Fujita, Masaya, Takahashi, Arata, Zhang, Min, Mishima, Masaaki, Kotani, Akira, Matsumoto, Takashi, Taguchi, Takeo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269671/
https://www.ncbi.nlm.nih.gov/pubmed/24352012
http://dx.doi.org/10.3390/molecules181215531
Descripción
Sumario:The reaction of 1,1-bis(triflyl)ethylene generated in situ with enolizable carbonyls yielded δ-oxo-1,1-bis(triflyl)alkane derivatives. Their acidities in both the gas and solution phases were determined.

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