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Diastereoselective [2+2] Photocycloaddition of Chiral Cyclic Enones with Olefins in Aqueous Media Using Surfactants

We conducted diastereodifferentiating [2+2] photocycloadditions of cyclo-hexenones modified with a chiral 8-(p-methoxy phenyl)menthyl auxiliary with olefins in water. Although the photoreaction didn’t proceed at all in pure water owing to very low solubility, the use of surfactants [sodium dodecyl s...

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Detalles Bibliográficos
Autores principales: Nishiyama, Yasuhiro, Shibata, Mikiko, Ishii, Takuya, Morimoto, Tsumoru, Tanimoto, Hiroki, Tsutsumi, Ken, Kakiuchi, Kiyomi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269683/
https://www.ncbi.nlm.nih.gov/pubmed/23358321
http://dx.doi.org/10.3390/molecules18021626