The Henry Reaction in [Bmim][PF(6)]-based Microemulsions Promoted by Acylase

An environmentally-friendly, enzyme-promoted procedure for the Henry reaction was first studied using water-in-[Bmim][PF(6)] microemulsions as reaction medium. The Amano acylase from Aspergillus oryzae showed better catalytic activity for the addition reactions of nitromethane with a series of aroma...

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Detalles Bibliográficos
Autores principales: Xia, Wen-Jian, Xie, Zong-Bo, Jiang, Guo-Fang, Le, Zhang-Gao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269850/
https://www.ncbi.nlm.nih.gov/pubmed/24284489
http://dx.doi.org/10.3390/molecules181113910
Descripción
Sumario:An environmentally-friendly, enzyme-promoted procedure for the Henry reaction was first studied using water-in-[Bmim][PF(6)] microemulsions as reaction medium. The Amano acylase from Aspergillus oryzae showed better catalytic activity for the addition reactions of nitromethane with a series of aromatic aldehydes, and a highest yield of 90% was obtained.

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