The Henry Reaction in [Bmim][PF(6)]-based Microemulsions Promoted by Acylase

An environmentally-friendly, enzyme-promoted procedure for the Henry reaction was first studied using water-in-[Bmim][PF(6)] microemulsions as reaction medium. The Amano acylase from Aspergillus oryzae showed better catalytic activity for the addition reactions of nitromethane with a series of aroma...

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Detalles Bibliográficos
Autores principales: Xia, Wen-Jian, Xie, Zong-Bo, Jiang, Guo-Fang, Le, Zhang-Gao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269850/
https://www.ncbi.nlm.nih.gov/pubmed/24284489
http://dx.doi.org/10.3390/molecules181113910
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author Xia, Wen-Jian
Xie, Zong-Bo
Jiang, Guo-Fang
Le, Zhang-Gao
author_facet Xia, Wen-Jian
Xie, Zong-Bo
Jiang, Guo-Fang
Le, Zhang-Gao
author_sort Xia, Wen-Jian
collection PubMed
description An environmentally-friendly, enzyme-promoted procedure for the Henry reaction was first studied using water-in-[Bmim][PF(6)] microemulsions as reaction medium. The Amano acylase from Aspergillus oryzae showed better catalytic activity for the addition reactions of nitromethane with a series of aromatic aldehydes, and a highest yield of 90% was obtained.
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spelling pubmed-62698502018-12-20 The Henry Reaction in [Bmim][PF(6)]-based Microemulsions Promoted by Acylase Xia, Wen-Jian Xie, Zong-Bo Jiang, Guo-Fang Le, Zhang-Gao Molecules Article An environmentally-friendly, enzyme-promoted procedure for the Henry reaction was first studied using water-in-[Bmim][PF(6)] microemulsions as reaction medium. The Amano acylase from Aspergillus oryzae showed better catalytic activity for the addition reactions of nitromethane with a series of aromatic aldehydes, and a highest yield of 90% was obtained. MDPI 2013-11-11 /pmc/articles/PMC6269850/ /pubmed/24284489 http://dx.doi.org/10.3390/molecules181113910 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Xia, Wen-Jian
Xie, Zong-Bo
Jiang, Guo-Fang
Le, Zhang-Gao
The Henry Reaction in [Bmim][PF(6)]-based Microemulsions Promoted by Acylase
title The Henry Reaction in [Bmim][PF(6)]-based Microemulsions Promoted by Acylase
title_full The Henry Reaction in [Bmim][PF(6)]-based Microemulsions Promoted by Acylase
title_fullStr The Henry Reaction in [Bmim][PF(6)]-based Microemulsions Promoted by Acylase
title_full_unstemmed The Henry Reaction in [Bmim][PF(6)]-based Microemulsions Promoted by Acylase
title_short The Henry Reaction in [Bmim][PF(6)]-based Microemulsions Promoted by Acylase
title_sort henry reaction in [bmim][pf(6)]-based microemulsions promoted by acylase
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269850/
https://www.ncbi.nlm.nih.gov/pubmed/24284489
http://dx.doi.org/10.3390/molecules181113910
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