Diels-Alder Reactions of 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione

12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted...

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Detalles Bibliográficos
Autores principales: Majetich, George, Zhang, Yong, Tian, Xinrong, Zou, Ge, Li, Yang, Wang, Yangyang, Hu, Shougang, Huddleston, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269985/
https://www.ncbi.nlm.nih.gov/pubmed/23771059
http://dx.doi.org/10.3390/molecules18066969
Descripción
Sumario:12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used.

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