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Diels-Alder Reactions of 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione
12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269985/ https://www.ncbi.nlm.nih.gov/pubmed/23771059 http://dx.doi.org/10.3390/molecules18066969 |
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author | Majetich, George Zhang, Yong Tian, Xinrong Zou, Ge Li, Yang Wang, Yangyang Hu, Shougang Huddleston, Eric |
author_facet | Majetich, George Zhang, Yong Tian, Xinrong Zou, Ge Li, Yang Wang, Yangyang Hu, Shougang Huddleston, Eric |
author_sort | Majetich, George |
collection | PubMed |
description | 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used. |
format | Online Article Text |
id | pubmed-6269985 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-62699852018-12-17 Diels-Alder Reactions of 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione Majetich, George Zhang, Yong Tian, Xinrong Zou, Ge Li, Yang Wang, Yangyang Hu, Shougang Huddleston, Eric Molecules Review 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used. MDPI 2013-06-14 /pmc/articles/PMC6269985/ /pubmed/23771059 http://dx.doi.org/10.3390/molecules18066969 Text en © 2013 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). |
spellingShingle | Review Majetich, George Zhang, Yong Tian, Xinrong Zou, Ge Li, Yang Wang, Yangyang Hu, Shougang Huddleston, Eric Diels-Alder Reactions of 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
title | Diels-Alder Reactions of 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
title_full | Diels-Alder Reactions of 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
title_fullStr | Diels-Alder Reactions of 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
title_full_unstemmed | Diels-Alder Reactions of 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
title_short | Diels-Alder Reactions of 12-Hydroxy-9(10→20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
title_sort | diels-alder reactions of 12-hydroxy-9(10→20)-5ah-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269985/ https://www.ncbi.nlm.nih.gov/pubmed/23771059 http://dx.doi.org/10.3390/molecules18066969 |
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