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H/D Isotope Effects in Hydrogen Bonded Systems

An extremely strong H/D isotope effect observed in hydrogen bonded A-H(…)B systems is connected with a reach diversity of the potential shape for the proton/deuteron motion. It is connected with the anharmonicity of the proton/deuteron vibrations and of the tunneling effect, particularly in cases of...

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Detalles Bibliográficos
Autores principales: Sobczyk, Lucjan, Obrzud, Monika, Filarowski, Aleksander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269986/
https://www.ncbi.nlm.nih.gov/pubmed/23591926
http://dx.doi.org/10.3390/molecules18044467