A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles

The ionic liquid 1-butyl-3-methylimidazolium methylselenite, [bmim][SeO(2)(OCH(3))], was successfully used as solvent in the catalyst-free preparation of 3-arylselenylindoles by the reaction of indole with ArSeCl at room temperature. The products were obtained selectively in good yields without the...

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Detalles Bibliográficos
Autores principales: Zimmermann, Everton G., Thurow, Samuel, Freitas, Camilo S., Mendes, Samuel R., Perin, Gelson, Alves, Diego, Jacob, Raquel G., Lenardão, Eder J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6269994/
https://www.ncbi.nlm.nih.gov/pubmed/23563858
http://dx.doi.org/10.3390/molecules18044081
Descripción
Sumario:The ionic liquid 1-butyl-3-methylimidazolium methylselenite, [bmim][SeO(2)(OCH(3))], was successfully used as solvent in the catalyst-free preparation of 3-arylselenylindoles by the reaction of indole with ArSeCl at room temperature. The products were obtained selectively in good yields without the need of any additive and the solvent was easily reused for several cycles with good results.

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